研究目的
To examine the effect of ambient pressure on the luminescent lifetime of Mg4FGeO6:Mn phosphors in different morphologies and evaluate the pressure sensitivity for various forms including phosphor powder, pressed phosphor disc, and chemically bonded coating.
研究成果
The pressure effect on luminescent lifetime varies with phosphor morphology: no effect for chemically bonded coating, weak for powder, and strong for pressed disc, aggravated at higher temperatures. This is attributed to atomic distance reduction under pressure, affecting the excited state movement. Calibration and measurement procedures must account for morphology to avoid errors, especially in in-flow applications.
研究不足
The study did not investigate dispersed phosphor particles in flow due to apparatus limitations. The pressed phosphor disc may not exactly simulate actual dispersed particles, and the pressure effect was more pronounced at higher temperatures and for agglomerated samples.
1:Experimental Design and Method Selection:
The study used a PMT-based measurement system to calibrate phosphor samples under varying pressures (20-200 kPa) and temperatures (298-873 K). The methodology involved fabricating samples with different morphologies and analyzing luminescent lifetime changes.
2:Sample Selection and Data Sources:
Samples included phosphor powder, pressed phosphor disc (simulating agglomerated particles), and chemically bonded phosphor coating. MFG powder with 1~2 μm size was used, prepared through drying and sieving.
3:List of Experimental Equipment and Materials:
Equipment included a hot/cold stage (Instec, USA), 405 nm diode laser (OEM-HD-405, CNI Laser, China), photomultiplier tube module (h9305-03, Hamamatsu, Japan), oscilloscope (Tektronix DPO2002B), and SEM for microstructure analysis. Materials included MFG phosphor, HPC binder (ZYP coatings, Oak Ridge, USA), and pure N2 gas.
4:Experimental Procedures and Operational Workflow:
Samples were placed on a silver platform in the hot/cold stage. Temperature was controlled via heating/cooling, and pressure was regulated with a pump. Laser excitation at 405 nm was used, and PMT signals were recorded and averaged over 512 samples. Data processing involved background subtraction, intensity normalization, and single-exponential decay fitting to acquire lifetime.
5:Data Analysis Methods:
Lifetime was derived from fitting decay curves. Statistical analysis compared results under different pressures and temperatures, with validation against existing literature data.
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diode laser
OEM-HD-405
CNI Laser
Excitation source for phosphor samples
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photomultiplier tube module
h9305-03
Hamamatsu
Capturing phosphorescence signal
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oscilloscope
DPO2002B
Tektronix
Recording PMT signals
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hot/cold stage
Instec
Controlling temperature for calibration experiments
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SEM
Analyzing microstructures of phosphor samples
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HPC binder
ZYP coatings
Adhesive material for chemically bonded phosphor coating
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