1：Experimental Design and Method Selection:

The study employs a one-pot photocatalytic strategy integrating reduction and oxidation half-reactions using CdS-based photocatalysts under visible light irradiation to synthesize nitrogen-containing compounds.

2：Sample Selection and Data Sources:

Nitrobenzene and benzyl alcohol are used as reactants; catalysts include bare CdS, MoS2/CdS, and Ni/CdS prepared via hydrothermal and photodeposition methods.

3：List of Experimental Equipment and Materials:

Chemicals include cadmium acetate, thioacetamide, nickel chloride, ammonium heptamolybdate, thiourea, benzyl alcohol, nitrobenzene, and others; equipment includes autoclave, Xe lamp with cut-off filter, GC, LC, GC-MS, SEM, XRD, XPS, BET surface area analyzer, UV-Vis spectrometer, and electrochemical workstation.

4：Experimental Procedures and Operational Workflow:

Catalysts are prepared and characterized; photocatalytic reactions are conducted in a flask under N2 atmosphere with visible light irradiation, followed by product analysis using GC, LC, and GC-MS.

5：Data Analysis Methods:

Conversion and selectivity are determined using GC with internal standard and GC-MS; mechanisms are proposed based on controlled experiments and characterization results.