研究目的
To investigate the long-term stability of composite materials modified with silver nanoparticles, focusing on mechanical and surface properties after incubation in deionized water.
研究成果
The composite materials based on ABS and PMMA with silver nanoparticles exhibit high stability in mechanical and surface properties after long-term incubation in deionized water. The modifier does not adversely affect the properties, suggesting potential use as stable implant materials, such as in middle ear prostheses. Future research should focus on in vivo studies and broader applications.
研究不足
The study is limited to in vitro conditions using deionized water, which may not fully replicate the complex biological environment of the human body. Potential agglomeration of nanoparticles and long-term effects beyond 12 months were not extensively explored.
1:Experimental Design and Method Selection:
The study involved preparing polymeric composites via extrusion and injection moulding using ABS and PMMA matrices with silver nanoparticles as a modifier. The methodology included mechanical testing, surface property evaluation, and stability assessment over time.
2:Sample Selection and Data Sources:
Samples were prepared from commercially available ABS (NovodurHDM203FC and NovodurHDM205FC) and PMMA (SG7 and SG10) polymers with silver nanoparticles (0.5% and 1% by weight). Data were collected before and after 6 and 12 months of incubation in deionized water at 37 ± 1 °C.
3:5% and 1% by weight). Data were collected before and after 6 and 12 months of incubation in deionized water at 37 ± 1 °C. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Equipment included a contact profilometer (HOMMEL-ETAMIC T1000 wave), drop shape analysis system (DSA 10 Mk2), scanning electron microscope (Nova Nano SEM FEG-200), universal testing machine (Inspect Table Blue 5 kN), and ultrasonic apparatus (MT541 device). Materials included silver nanoparticles from NanoAmor, deionized water, and polymer granules.
4:Experimental Procedures and Operational Workflow:
Granulate was dried, silver nanoparticles were homogenized with polymer granules using a screw, melted twice, injected into a mould, cooled, and extracted. Samples were incubated in deionized water, and measurements (roughness, contact angle, SEM, tensile strength, Young's modulus, ultrasound velocity) were performed at specified intervals.
5:Data Analysis Methods:
Data were analyzed using statistical techniques, with parameters averaged from multiple measurements and expressed as mean ± standard deviation.
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contact profilometer
HOMMEL-ETAMIC T1000 wave
Jenoptik AG
Evaluating the arithmetical mean roughness (Ra) of the surface
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scanning electron microscope
Nova Nano SEM FEG-200
FEI
Examining the samples' microstructure in low vacuum conditions
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drop shape analysis system
DSA 10 Mk2
Kruss
Determining the static water contact angle by the sessile drop method
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universal testing machine
Inspect Table Blue 5 kN
Hegewald&Peschke
Determining tensile strength and Young's modulus with a 5 kN load cell
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ultrasonic apparatus
MT541 device
Measuring ultrasound velocities using 1 MHz transducers for longitudinal waves
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silver nanoparticles
NanoAmor
Used as a modifying additive in the polymer composites
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polymer granules
NovodurHDM203FC, NovodurHDM205FC, SG7, SG10
Used as polymer matrices for the composites
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