研究目的
To investigate the electric field-induced strains of BZT ferroelectric ceramics with an emphasis on the hysteresis and electrostrictive coefficient, aiming to develop lead-free alternatives for high-precision displacement actuators.
研究成果
BZT ceramics exhibit high electric field-induced strains (>0.15%) with ultra-low hysteresis (<8%) and a high electrostrictive coefficient Q33 (up to 0.0452 m4/C2), making them promising for use in high-precision displacement actuators as lead-free alternatives.
研究不足
The study is limited to a specific composition range (x=0.02 to 0.1) of BZT ceramics; potential variations due to processing parameters like density and grain size are noted, and the absence of strong relaxor behavior may restrict broader applicability.
1:Experimental Design and Method Selection:
The study uses a conventional solid state reaction method to fabricate Ba(ZrxTi1-x)O3 ceramics with x from
2:02 to 1, focusing on structural and electrical property analysis, particularly electrostrictive effects. Sample Selection and Data Sources:
Ceramic samples are prepared using high-purity oxide powders (BaCO3, TiO2, ZrO2) in stoichiometric ratios, with compositions varied by x value.
3:List of Experimental Equipment and Materials:
Equipment includes X-ray diffractometer (XRD, PANalytical), multi-frequency LCR meter (E4980A, Agilent), ferroelectric testing system (TF analyzer 2000, aixACCT), and laser interferometer vibrometer (SP-S 120, SIOS Me?technik GmbH). Materials are BaCO3 (99%), TiO2 (99%), ZrO2 (
4:96%) from Sinopharm Chemical Reagent Co., Ltd. Experimental Procedures and Operational Workflow:
Powders are mixed by planetary ball milling, calcined at 1250°C, pressed into disks, cold isostatic pressed at 250 MPa, and sintered at 1400°C. XRD is used for structural analysis, dielectric properties are measured from -120°C to 160°C, and P-E/S-E curves are collected at 1 Hz with Emax of 60 kV/cm.
5:Data Analysis Methods:
Data are analyzed using fitting based on electrostrictive equations, with hysteresis calculated as ΔSE/2/Smax×100%, and parameters like Q33 derived from strain-polarization relationships.
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X-ray diffractometer
PANalytical
PANalytical
Used for identifying crystal structures of ceramic samples through XRD analysis.
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LCR meter
E4980A
Agilent
Used for measuring temperature-dependent relative dielectric permittivity and loss at multiple frequencies.
E4980A/E4980AL Precision LCR Meter
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Ferroelectric testing system
TF analyzer 2000
aixACCT
Used for collecting bipolar polarization-electric field hysteresis loops and strain-electric field curves.
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Laser interferometer vibrometer
SP-S 120
SIOS Me?technik GmbH
Used in conjunction with the ferroelectric testing system for strain measurements.
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Planetary ball mill
Used for mixing precursor powders in alcohol.
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Cold isostatic press
Used for condensing pressed disks under high pressure.
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