研究目的
To develop a novel TiO2/CNTs composite filter for high-efficiency removal and photocatalytic degradation of oil particles, particularly from cooking fumes, addressing limitations of conventional filtration methods.
研究成果
The TiO2/CNTs-filter demonstrates superior filtration performance with higher efficiency than HEPA filters, lower pressure drop increase, and effective photocatalytic degradation of oil particles. It shows promise for applications in cooking fume treatment due to its simplicity, high efficiency, and self-cleaning properties, though further optimization and real-world testing are needed.
研究不足
The study is limited to laboratory-scale experiments with oleic acid as a model pollutant; real-world applications may involve variable conditions. Photocatalytic degradation is surface-layer limited, not effective for deeply embedded particles. The initial pressure drop, while close to HEPA, could be further optimized, and long-term stability and cost-effectiveness were not fully addressed.
1:Experimental Design and Method Selection:
The study involved synthesizing TiO2/CNTs-filters using chemical vapor deposition (CVD) for CNTs growth on nickel foam modified with an Al2O3 barrier layer, followed by dip-coating with TiO2 nanoparticles (Degussa P25). Filtration and photocatalytic performance tests were conducted to evaluate efficiency and degradation rates.
2:5). Filtration and photocatalytic performance tests were conducted to evaluate efficiency and degradation rates. Sample Selection and Data Sources:
2. Sample Selection and Data Sources: Nickel foams (thickness ~3 mm, PPI 110, Ni≥99.9 wt.%) were used as substrates. Oleic acid aerosols served as mock oil mist for testing.
3:9 wt.%) were used as substrates. Oleic acid aerosols served as mock oil mist for testing. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Equipment included SEM (FEI Quanta 200), TEM (FEI Tecnai G20), contact angle goniometer (Powereach JC2000D), pore-size distribution analyzer (GaoQ PSDA-20), ELPI (DEKATI), pressure transmitter (Asmik MIK-9600D), electron balance (Sartorius), UV light (Cnlight, 15 W, 253.7 nm), digital radiometer (Sentry ST-512), and type K thermocouple. Materials included aluminium isopropoxide, xylene, ferrocene, Degussa P25 TiO2, hydrochloric acid, and oleic acid.
4:7 nm), digital radiometer (Sentry ST-512), and type K thermocouple. Materials included aluminium isopropoxide, xylene, ferrocene, Degussa P25 TiO2, hydrochloric acid, and oleic acid. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Synthesis involved CVD growth of CNTs at 800°C with xylene/ferrocene solution, purification with HCl, dip-coating with TiO2 suspension, and calcination. Filtration tests measured pressure drop and efficiency using oleic acid aerosols; photocatalytic tests measured mass loss under UV irradiation.
5:Data Analysis Methods:
Data were analyzed using equations for pressure drop (proportional to face velocity), filtration efficiency, quality factor, and degradation rates, with comparisons to HEPA filters.
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Scanning Electron Microscopy
FEI Quanta 200
FEI
Characterization of surface morphology of composite filters
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Transmission Electron Microscopy
FEI Tecnai G20
FEI
Observation of microstructure of CNTs and TiO2/CNTs
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Contact Angle Goniometer
JC2000D
Powereach
Measurement of contact angle of oleic acid on the filter
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Pore-size Distribution Analyzer
PSDA-20
GaoQ
Testing pore size distribution of filters
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Electrical Low Pressure Impactor
ELPI
DEKATI
Measurement of aerosol concentration and size distribution
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Pressure Transmitter and Recorder
MIK-9600D
Asmik
Online measurement of pressure drop of filters
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Electron Balance
Sartorius
Sartorius
Measurement of weight change of pollutant on filters
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UV Light
15 W
Cnlight
Providing ultraviolet radiation for photocatalytic degradation
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Digital Radiometer
ST-512
Sentry
Measurement of radiation intensity on filter surface
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Thermocouple
Type K
Measurement of temperature during photocatalytic reaction
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TiO2 Nanoparticles
Degussa P25
Degussa
Photocatalyst for degradation of oil particles
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Nickel Foam
Substrate for CNTs growth and filter frame
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