研究目的
To investigate the effect of swift heavy ions irradiation on residual stress, structural changes, and surface modifications in palladium films deposited on 6H-SiC substrates.
研究成果
Swift heavy ion irradiation of Pd films on 6H-SiC leads to increased crystallinity, grain growth, and formation of PdSi and Pd2Si at higher fluences. Tensile stress decreases with irradiation due to compressive stress induction and temperature increases. Surface morphology shows granule size increase and agglomeration. These findings are significant for applications in nuclear reactors and hydrogen sensors, suggesting that irradiation can alter material properties, but further studies are needed for broader conditions.
研究不足
The study is limited to specific ion energy and fluences; results may vary with different parameters. The columnar grain structure in films may lead to discrepancies between XRD and SEM measurements. The research focuses on room temperature irradiation; effects at other temperatures are not explored.
1:Experimental Design and Method Selection:
The study involved irradiating Pd films on 6H-SiC with swift heavy ions (Xe26+ at 167 MeV) at different fluences to observe phase changes, stress variations, and surface morphology. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used for analysis.
2:Sample Selection and Data Sources:
Semi-insulating 6H-SiC single-crystal wafers were cut into 5 × 5 mm2 pieces, chemically cleaned, and Pd films of about 385 nm thickness were deposited by resistive evaporation.
3:List of Experimental Equipment and Materials:
Equipment included a diamond scriber for cutting, resistive evaporation system for deposition, Inficon deposition rate monitor, Xe26+ ion irradiation facility at JINR, Bruker-AXS D8 Advance diffractometer for XRD, Bruker D8 Discover diffractometer for stress measurements, Zeiss Ultra 55 SEM for morphology, and SRIM-2013 software for simulations. Materials included Pd, 6H-SiC wafers, methanol, HF, deionized water.
4:Experimental Procedures and Operational Workflow:
Samples were prepared by cleaning and depositing Pd, irradiated at room temperature with specified fluences, and analyzed using XRD for phase identification and stress, and SEM for surface examination. Stress measurements involved multiple azimuth and tilt angles.
5:Data Analysis Methods:
XRD data were analyzed using Scherrer equation for crystallite size and proprietary Leptos v6.02 software for stress-strain determination. SEM images were examined for morphological changes.
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Bruker-AXS D8 Advance diffractometer
D8 Advance
Bruker
Used for X-ray diffraction (XRD) phase identification with theta-theta goniometer.
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Bruker D8 Discover diffractometer
D8 Discover
Bruker
Used for stress-strain measurements with theta-2theta goniometer in side-inclination mode.
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Zeiss Ultra 55 field emission scanning electron microscope
Ultra 55
Zeiss
Used for scanning electron microscopy (SEM) to examine surface morphology.
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diamond scriber
Used for cutting the 6H-SiC wafer into 5 × 5 mm2 pieces.
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resistive evaporation system
Used for depositing Pd films on the SiC substrates.
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Inficon deposition rate monitor
Inficon
Used to monitor the Pd thickness during the deposition process.
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Xe26+ ion irradiation facility
Joint Institute for Nuclear Research (JINR)
Used for irradiating samples with swift heavy ions at specified energy and fluences.
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SRIM-2013 software
2013
Monte Carlo computer programme used for calculating ion ranges and energy loss.
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Leptos software
v6.02
Proprietary software used for stress-strain determination from XRD data.
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