1：Experimental Design and Method Selection:

The study involved preparing TiO2@Cf via hydrothermal method and assembling memristor crossbars on a polyimide film. The resistive switching behavior was analyzed using electrical measurements and various characterization techniques to understand the mechanism based on oxygen vacancy migration and Fowler-Nordheim tunneling.

2：Sample Selection and Data Sources:

Carbon fibers were used as the base material, treated by calcination and ultrasonic cleaning. TiO2 nanorods were grown on them hydrothermally. Data were obtained from electrical tests and material characterizations.

3：List of Experimental Equipment and Materials:

Equipment included an autoclave for hydrothermal synthesis, X-ray diffraction (XRD) system, X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance (EPR) spectrometer, scanning electron microscopy (SEM), high-resolution transmission electron microscope (HRTEM), selected-area electron diffraction (SAED), and a Keithley 4200-SCS semiconductor characterization system. Materials included carbon fibers, hydrochloric acid, titanium butoxide, polyimide film, and copper for electrodes.

4：Experimental Procedures and Operational Workflow:

Carbon fibers were calcined and cleaned, then subjected to hydrothermal reaction with titanium butoxide and HCl at 150°C for 3 hours. The resulting TiO2@Cf were woven into textiles and fixed on a PI film with sputtered copper electrodes. Electrical measurements were performed with voltage sweeps, and material characterizations (XRD, XPS, EPR, SEM, TEM) were conducted to analyze structure and composition.

5：Data Analysis Methods:

Data were analyzed using fitting functions for XPS spectra (Voigt function), linear fitting for Fowler-Nordheim tunneling plots, and statistical evaluation of endurance cycles. Software tools specific to the equipment were used, but not specified in the paper.