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Variable densification of reduced graphene oxide foam into multifunctional high-performance graphene paper
摘要： Super-flexible, electrically and thermally conductive graphene-based papers are in great demand in the fields of electronics and supercapacitors. However, the applications of graphene-based papers are limited either by their brittleness, small scale, or by their unsatisfactory thermal conductivity. Conventionally, such papers are fabricated by vacuum-assisted filtration, direct evaporation, electrospray coating, or wet spinning. Here we propose a novel strategy, namely, direct densification of reduced graphene oxide foam, to fabricate large-scale multifunctional graphene papers. The graphene paper density could be adjusted by applying different loads. The densities of the graphene papers varied from 0.32 g cm?3 to 1.85 g cm?3. The thermal conductivity, tensile stress, electrical conductivity and electromagnetic interface shielding effectiveness increased with an increase in the density of the graphene paper. When the density of the graphene paper reached 1.85 g cm?3, the tensile stress was up to 50.4 MPa with strain of 4%, the thermal conductivity was 1103 W m?1 K?1 at room temperature and there was high electrical conductivity of 1.1 × 10? S m?1, as well as an electromagnetic interference (EMI) shielding effectiveness of 77.2 dB. Our new strategy is very promising in terms of controlling the thickness, density, and size of graphene paper.
关键词： graphene paper,densification,EMI shielding,electrical conductivity,thermal conductivity
更新于2025-09-19 17:15:36
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Distributed Thermal Response Tests Using a Heating Cable and Fiber Optic Temperature Sensing
摘要： Thermal response tests are used to assess the subsurface thermal conductivity to design ground-coupled heat pump systems. Conventional tests are cumbersome and require a source of high power to heat water circulating in a pilot ground heat exchanger. An alternative test method using heating cable was verified in the field as an option to conduct this heat injection experiment with a low power source and a compact equipment. Two thermal response tests using heating cable sections and a continuous heating cable were performed in two experimental heat exchangers on different sites in Canada and France. The temperature evolution during the tests was monitored using submersible sensors and fiber optic distributed temperature sensing. Free convection that can occur in the pipe of the heat exchanger was evaluated using the Rayleigh number stability criterion. The finite and infinite line source equations were used to reproduce temperature variations along the heating cable sections and continuous heating cable, respectively. The thermal conductivity profile of each site was inferred and the uncertainly of the test was evaluated. A mean thermal conductivity 15% higher than that revealed with the conventional test was estimated with heating cable sections. The thermal conductivity evaluated using the continuous heating cable corresponds to the value estimated during the conventional test. The average uncertainly associated with the heating cable section test was 15.18%, while an uncertainty of 2.14% was estimated for the test with the continuous heating cable. According to the Rayleigh number stability criterion, significant free convection can occur during the heat injection period when heating cable sections are used. The continuous heating cable with a low power source is a promising method to perform thermal response tests and further tests could be carried out in deep boreholes to verify its applicability.
关键词： fiber optic,geothermal,heating cable,thermal response test,thermal conductivity
更新于2025-09-19 17:15:36
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Synthesis, characterization, and application of fluorescent electrically conducting copolymer/metal-oxide nanocomposites
摘要： Solution polymerization of aniline in the presence of fluorescent organic dyes was carried out at 0–5°C for 2 h under nitrogen atmosphere with FeCl3 as an initiator. The copolymers were prepared under different experimental conditions. The prepared copolymers were characterized by various analytical tools. The electrical conductivity was measured. From the absorbance and emission intensity values the order of reaction was calculated. Further, its application toward the reduction of nitrophenol was done and the apparent rate constant (Kapp) was calculated. The Fourier Transform Infra Red (FTIR) spectrum confirmed the presence of benzenoid, quinonoid, and azo functionalities.
关键词： characterization,morphology,Copolymers,synthesis,conductivity,reduction
更新于2025-09-19 17:15:36
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Facile organic surfactant removal of various dimensionality nanomaterials using low-temperature photochemical treatment
摘要： Deep ultraviolet (DUV)-treatment is an efficient method for the removal of high-energy-barrier polymeric or aliphatic organic ligands from nanomaterials. Regardless of morphology and material, the treatment can be used for nanoparticles, nanowires, and even nanosheets. The high-energy photon irradiation from low-pressure mercury lamps or radio frequency (RF) discharge excimer lamps could enhance the electrical conductivity of various nanomaterial matrixes, such as Ag nanoparticles, Bi2Se3 nanosheets, and Ag nanowires, with the aliphatic alkyl chained ligand (oleylamine; OAm) and polymeric ligand (polyvinyl pyrrolidone; PVP) as surfactants. In particular, Ag nanoparticles (AgNPs) that are DUV-treated with polyvinyl pyrrolidone (PVP) for 90 min (50–60 °C) exhibited a sheet resistance of 0.54 Ω □?1, while thermal-treated AgNP with PVP had a sheet resistance of 7.5 kΩ □?1 at 60 °C. The simple photochemical treatment on various dimensionality nanomaterials will be an efficient sintering method for flexible devices and wearable devices with solution-processed nanomaterials.
关键词： nanomaterials,organic ligand removal,photochemical treatment,electrical conductivity,deep ultraviolet
更新于2025-09-19 17:15:36
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Colloidal Synthesis of Bulk-Bandgap Lead Selenide Nanocrystals
摘要： Lead selenide quantum dots (QDs) are low-bandgap IV-VI semiconducting nanomaterials that have been studied for a variety of applications. Their preparation using colloidal methods can create small spherical to larger cubic nanocrystals, with an upper limit of ～17 nm reported to date. Here we describe methods for preparing cubic PbSe nanocrystals over a 20–40 nm size range using a two-step procedure. Specifically, ～10 nm PbSe QDs are generated using the rapid injection method, the products from which are overcoated with additional lead and selenium precursors. The use of two lead reagents were studied; lead oleate resulted in a maximum of 20 nm cubes, while more reactive lead hexyldecanoate resulted in much larger nanomaterials with bulk bandgaps. However, PbSe samples prepared with lead hexyldecanoate also contained agglomerates. Special care must be taken when characterizing larger strained nanomaterials with X-ray powder diffraction, for which the Scherrer equation is inadequate. A more rigorous approach using the Williamson–Hall method provides characterizations that are consistent with electron microscopy analysis.
关键词： lead selenide,nanomaterials,conductivity,semiconductor,quantum dots
更新于2025-09-19 17:15:36
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Thermophysical Properties of Silicon-Carbide-Based Ceramic Composite Materials Obtained by Spark Plasma Sintering (SPS)
摘要： The factors influencing the thermal conductivity of SiC-based ceramic composite materials obtained by the spark plasma sintering technology with relative density 99% and B4C, AlN, Si3N4, Y2O3, Al2O3, and HfB2 as additives are examined. The thermophysical properties were determined in the temperature range 20 – 1300°C: specific heat, thermal diffusivity, and thermal conductivity of composites. The thermal diffusivity and specific heat were measured by the laser-spark method. The measurements of specific heat are supplemented by measurements performed with a DSC and adiabatic calorimeter. The thermal conductivity is calculated using data on the thermal diffusivity, specific heat, and density.
关键词： laser flash method,specific heat,adiabatic calorimeter,thermal conductivity,ceramic composite materials,thermal diffusivity,thermophysical properties,differential scanning calorimetry (DSC)
更新于2025-09-19 17:15:36
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Manufacturing Graphene-Encapsulated Copper Particles by Chemical Vapor Deposition in a Cold Wall Reactor
摘要： Functional fillers, such as Ag, are commonly employed for effectively improving the thermal or electrical conductivity in polymer composites. However, a disadvantage of such a strategy is that the cost and performance cannot be balanced simultaneously. Therefore, the drive to find a material with both a cost efficient fabrication process and excellent performance attracts intense research interest. In this work, inspired by the core–shell structure, we developed a facile manufacturing method to prepare graphene-encapsulated Cu nanoparticles (GCPs) through utilizing an improved chemical vapor deposition (CVD) system with a cold wall reactor. The obtained GCPs could retain their spherical shape and exhibited an outstanding thermal stability up to 179 °C. Owing to the superior thermal conductivity of graphene and excellent oxidation resistance of GCPs, the produced GCPs are practically used in a thermally conductive adhesive (TCA), which commonly consists of Ag as the functional filler. Measurement shows a substantial 74.6 % improvement by partial replacement of Ag with GCPs.
关键词： graphene,copper particles,cold wall reactor,thermal conductivity,oxidation resistance
更新于2025-09-19 17:15:36
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Cellulose nanofiber nanocomposites with aligned silver nanoparticles
摘要： Celluloses have attracted much attention as sustainable and abundant materials. Herein, we focus on nanocomposites based on the oxidation-treated nano-sized fibrillated celluloses, namely TOCNs. The silver nanoparticles (AgNPs) were prepared in TOCN aqueous dispersion. Generally, the AgNPs are quickly agglomerated after preparation. For the inhibition of the agglomeration of AgNPs, it is required that AgNPs were prepared under the chelation of TOCN, followed by reduction therein. Therefore, AgNPs possessed the nano-scaled radii and aligned along the TOCN from the atomic force microscopic measurements. The thermal stabilities and mechanical properties were increased. The anisotropic thermal conductivities originated from the orientation of TOCN in nanocomposites were observed. The loading of the large amounts of AgNP fillers led to the drastic increase of the thermal and electrical conductivities. The conductive paths of heat and electron were formed by the contact of AgNP with each other. We functionalized the TOCN papers through the loading of AgNPs and the obtained nanocomposites sheets served as conductors.
关键词： Cellulose nanofiber,mechanical property,TEMPO-mediated oxidation,silver nanoparticle,thermal conductivity
更新于2025-09-19 17:15:36
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Heat and charge transport in bulk semiconductors with interstitial defects
摘要： Interstitial defects are inevitably present in doped semiconductors that enable modern-day electronic, optoelectronic, or thermoelectric technologies. Understanding the stability of interstitials and their bonding mechanisms in the silicon lattice was accomplished only recently with the advent of first-principles modeling techniques, supported by powerful experimental methods. However, much less attention has been paid to the effect of different naturally occurring interstitials on the thermal and electrical properties of silicon. In this work, we present a systematic study of the variability of heat and charge transport properties of bulk silicon, in the presence of randomly distributed interstitial defects (Si, Ge, C, and Li). We find through atomistic lattice dynamics and molecular dynamics studies that interstitial defects scatter heat-carrying phonons to suppress thermal transport—1.56% of randomly distributed Ge and Li interstitials reduce the thermal conductivity of silicon by ～30 and 34 times, respectively. Using first-principles density functional theory and semiclassical Boltzmann transport theory, we compute electronic transport coefficients of bulk Si with 1.56% neutral Ge, C, Si, and Li interstitials, in energetically favorable hexagonal, tetrahedral, split-interstitial, and bond-centered sites. We demonstrate that hexagonal-Si and hexagonal-Ge interstitials minimally impact charge transport. As an illustration of the relevance of this work for practical applications, we predict the thermoelectric property of an experimentally realizable bulk Si sample that contains Ge interstitials in different symmetry sites. Our research establishes a direct relationship between the variability of structures dictated by fabrication processes and heat and charge transport properties of silicon. The relationship provides guidance to accurately estimate performance of Si-based materials for various technological applications.
关键词： electronic transport,thermoelectric properties,interstitial defects,silicon,thermal conductivity
更新于2025-09-19 17:15:36
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[IEEE 2018 IEEE International Symposium on Antennas and Propagation & USNC/URSI National Radio Science Meeting - Boston, MA, USA (2018.7.8-2018.7.13)] 2018 IEEE International Symposium on Antennas and Propagation & USNC/URSI National Radio Science Meeting - Analysis of Waves Propagation on Magnetized Graphenes Using Surface Boundary Condition FDTD
摘要： In this paper, the finite-difference time-domain (FDTD) method is presented to study the magnetically biased graphene. With the introduction of the surface resistivity, the biased graphene can be taken as a two-dimensional anisotropic surface with zero thickness, which avoids the tiny spatial cell in FDTD simulation. Because of gyrotropy of the material, we calculate the average electric field over the sheet and reconstruct the electric fields after every time-marching step. The derived difference equations result in easy programming. Numerical results are presented to show the accuracy of our approach.
关键词： surface boundary condition,magnetized graphene,surface conductivity,Finite-difference time-domain
更新于2025-09-19 17:15:36