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Improving performance of thermally activated delayed fluorescence emitter by extending its LUMO distribution; 通过扩展LUMO分布提高热激活延迟荧光材料的性能;
摘要： An optimized compound 9-(9,9-dimethylacridin-10(9H)-yl)-6H-benzo[c]ch-romen-6-one (MAB) was designed and synthesized based on our previously reported TADF emitter 6-(9,9-dimethylacridin-10(9H)-yl)-3-methyl-1H-isochromen-1-one (MAC) to further improve the performance of thermally activated delayed fluorescence (TADF) emitters. With the additional phenyl in coumarin-contained plane, MAB possesses an extended distribution of the lowest unoccupied molecular orbitals (LUMO), and thus realizes reduced electron exchange between the frontier molecular orbitals and a stretched molecular dipole moment compared with MAC. MAB based organic light-emitting diode (OLED) exhibits a remarkable maximum external quantum efficiency (EQE) of 21.7%, which is much better than the maximum EQE of MAC-based OLED with a value of 12.8%. Our work proves that extending the distribution of LUMO is a simple but effective method to improve the efficiency of TADF emitter.
关键词： lumo distribution,external quantum efficiency,thermally activated delayed fluorescence,organic light-emitting diode
更新于2025-09-23 15:21:21
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Exploiting lateral current flow due to doped layers in semiconductor devices having crossbar electrodes
摘要： Organic electronic devices such as light-emitting diodes, solar cells or rectifying diodes normally have a sandwich layer architecture stacked between the electrodes in a crossbar layout. Often however, the side effects of operating the devices in such an arrangement are either ignored or give rise to misinterpretations regarding the device performance or layer quality. For the sake of simplicity, device currents are typically assumed to exclusively flow in the direction vertical to the substrate, even though the conductivity of doped organic layers is high and gives rise to significant lateral current flows. Here, we study the vertical and lateral charge up along the n-doped and the p-doped layers as well as the resulting capacitance increase of charging the intrinsic layer outside the active area. We observe that controlling such lateral charging by structuring the doped layers can reduce the leakage current dramatically. We employ impedance spectroscopy to investigate the lateral charging responsibility for the capacitance increase at low frequencies. Modeling of the devices by a distributed RC circuit model yields information about the thickness, the conductivity, and the corresponding activation energy of both, the n-doped and the p-doped layers, simultaneously. We demonstrate that the capacitive effects from lateral charging can easily be misinterpreted as trap states in capacitance frequency characteristics. However, correct analysis with the proposed model actually yields rich and detailed post-fabrication information which can be utilized in device failure and degradation tests. Moreover, our results will aid the design and characterization of new electronic devices where lateral charge flow is part of the device concept.
关键词： Parasitic current,Leakage current,Impedance spectroscopy,Crossbar electrodes,Lateral current flow,Organic light-emitting diode,Capacitance,Organic solar cell,Structuring
更新于2025-09-23 15:21:21
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Physiological responses of pepper seedlings to various ratios of blue, green, and red light using LED lamps
摘要： Chlorophyll absorbs green light less e?ciently than it absorbs other wavelengths in the visible spectrum so green light drives photosynthesis less e?caciously. Green light emitting diodes (LEDs) are also less e?cacious at converting electrical energy into photons than their red and blue counterparts. Consequently, most photosynthetic LED lighting has been designed without including green wavelengths in the spectrum. Plant physiological research has largely focused on light signal responses to red, far-red and blue light, but recent e?orts suggest other wavebands may play an important role in plant development and photosynthetic activity. We have examined the role of monochromatic red, blue and green light and combinations of these colors with regard to seedling growth of bell pepper. The shoots of pepper plants grown under monochromatic green light had greater leaf area and lower speci?c leaf weight (mg cm?2) than those grown under monochromatic blue or red light. Green light also resulted in taller plants with greater dry weight and thicker stems relative to plants grown with blue light. A broad spectrum including red, green, and blue wavelengths resulted in the highest shoot dry weight and plant compactness.
关键词： Plant physiology,Green light,Blue light,Capsicum annuum,Red light,Light emitting diode
更新于2025-09-23 15:21:01
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A Lifetime Performance Analysis of LED Luminaires Under Real-Operation Profiles
摘要： Light-emitting diode (LED)-based lighting is the most dominant lighting solution in the current era since it is energy-efficient and long-lasting. Hence, performance analysis of the LEDs throughout its lifetime is of prime importance. The work presented in this article provides insight on degradation analysis of the LED luminaire inclusive of the LED driver in real operating ambient conditions and investigates the performance of both LED light engine and LED driver throughout the period of its lifetime. To represent the practical scenario of LED lighting system usage in commercial applications, analysis of switching cycles on the performance of LED luminaires is also studied. The outcome of this article suggests that LED luminaire under study tends to fail due to lumen degradation, followed by color shift represented by Duv and then lastly by driver failure. Scanning electron microscope and energy-dispersive spectroscopy (SEM-EDS) analysis suggests the corrosion of Ag mirror resulting in lumen output reduction and, thus, is the main reason for the failure of LED luminaire. This provides an insight into the LED manufacturing companies to have better estimate on lifetime of LED luminaires and also the necessity to improve the LEDs’ performance such that luminaires will have longer lifetime as claimed.
关键词： Life estimation,operating cycles,light-emitting diode (LED) luminaire,lumen degradation
更新于2025-09-23 15:21:01
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Evaluation of a Ultraviolet B Light Emitting Diode (LED) for Producing Vitamin D <sub/>3</sub> in Human Skin
摘要： Aim: A commercially available light emitting diode (LED) that transmitted narrow band ultraviolet B (UVB) radiation was evaluated for its efficacy and efficiency to produce vitamin D3 in human skin. Materials and Methods: Human skin samples were obtained from surgical procedures. The LED had peak emission wavelength of 295 nm. Skin samples were exposed to the UVB-LED for varying times and then were analyzed by high-pressure liquid chromatography (HPLC) to determine the vitamin D3 content. Results: There was a statistically significant time- and dose- dependent increase in the percent of 7-dehydrocholesterol that was converted to vitamin D3 in the skin type II samples; 1.3%±0.5, 2.3%±0.6 and 4.5%±1.67 after exposure to 0.75 (11.7 mJ/cm2), 1.5 (23.4 mJ/cm2) and 3 (46.8 mJ/cm2) minimal erythemal doses (MEDs), respectively. Conclusion: The UVB-LED was effective and efficient in generating vitamin D3 in human skin, in vitro. The amount of vitamin D3 production increased in a dose-dependent fashion with increased UVB energy. UVB-LEDs can be developed for devices that can efficiently produce vitamin D3 in human skin.
关键词： vitamin D3,human skin,ultraviolet B radiation,Previtamin D3,ultraviolet radiation light emitting diode (LED)
更新于2025-09-23 15:21:01
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Carbazole-modified polyphenylene ether as host materials for high efficiency phosphorescent organic light-emitting diodes
摘要： Two novel polymeric hosts called PPO-Cz and PPO-3Cz for solution-processed green phosphorescent organic light-emitting devices have been designed and synthesized by incorporating electron-donor carbazole units with polyphenylene ether. In order to simplify the synthesis route and save cost, we attached the classic carbazole units directly to the side chain of the polyphenylene ether. This molecular design endows these two polymeric hosts with good thermal stability and high triplet energy levels. PPO-Cz- and PPO-3Cz-based emissive-layer green phosphorescent organic light-emitting diodes were fabricated with simplified device configuration by solution-processed using Ir(mppy)3 as a dopant. These devices exhibited lower turn on voltages. Moreover, the PPO-3Cz-based solution processed device showed maximum current efficiency and external quantum efficiency of 31.8 cd/A and 9.3%, respectively. This result demonstrated that the newly synthesized, polymeric hosts were advantageous for fabrication of highly efficient green phosphorescent organic light-emitting diodes.
关键词： Organic light emitting diode,Polyphenylene ether,Modify,Carbazole,Polymeric host
更新于2025-09-23 15:21:01
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[IEEE 2020 Moscow Workshop on Electronic and Networking Technologies (MWENT) - Moscow, Russia (2020.3.11-2020.3.13)] 2020 Moscow Workshop on Electronic and Networking Technologies (MWENT) - Measurement of the Dynamic Characteristics of Separate Spectral Bands of the LEDs Electroluminescence Spectra
摘要： A method for measuring the 3 dB frequency of the full modulation of separate spectral components of electroluminescence spectrum of light-emitting diodes (LEDs) is described. The method consists in passing through the LED a series of current pulses having the shape of a meander, and the emission spectrum of the LED is measured by a spectrometer OceanOptics USB2000+ in the mode of signal accumulation. As the pulse frequency increases, the intensity of all spectral components of the LED emission spectrum decreases. The frequency at which the optical signal decreases 1.19 times relative to the level measured at a low frequency is taken as the 3 dB frequency of the separate spectral component of the LED electroluminescence spectrum. By using the pulse signal it is possible to increase the sensitivity of the measuring means compared to the measuring means using the harmonic test signal. A description of the hardware-software complex implementing said measurement method is presented. The results of testing the measuring complex by the electroluminescence spectra of commercial green InGaN-based LEDs at the current range of 10-5...10-2 A and the current frequency range of 0.001...10 MHz are presented. The developed hardware-software complex and the method for estimating the spectral recombination parameters of heterojunction LEDs can be used both for the purpose of diagnosing the quality of LEDs and in developing structural and technological solutions for creating new light-emitting structures.
关键词： electroluminescence spectra,measuring complex,measurement method,3 dB frequency,light-emitting diode (LED),radiative and nonradiative charge carriers lifetime
更新于2025-09-23 15:21:01
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[IEEE 2018 15th IEEE India Council International Conference (INDICON) - Coimbatore, India (2018.12.16-2018.12.18)] 2018 15th IEEE India Council International Conference (INDICON) - Safety of Light Emitting Diode (LED) Based Domestic Lighting in Rural Context
摘要： As per 2011 census, 69% of Indians live in the rural settings, who are primarily dependent on subsistence agriculture. Rural house-holds use power lighting, operating household appliances and agricultural works. Home-lighting is one of the major components of power consumption in less affluent rural households. Many rural houses use kerosene lamps, lanterns, candles and inverter-based electric lamps as a light source. Therefore, artificial lighting in a rural scenario is expected to have certain characteristics such as a) illumination; b) Low cost; c) Low power appropriate consumption; d) Long life; e) Low maintenance. Light-emitting Diode (LED) has been a revolution in such scenarios with its long life, low cost, less power consumption and lesser pollution. While nowadays, low-cost white (cool daylight) LED lights have overtaken the Indian lighting market and are projected to reach $2.2billion by 2021. However, some reports have raised concern regarding various health hazards (circadian rhythm disruption and harm to the human eyes) due to sharp blue-peak in LED lights. Since the scientific literature is still inconclusive about the photo-biological safety of blue-rich white LEDs, usage of LEDs needs more awareness. The aim of this study is to assess the fraction of radiation in the blue region of the entire spectrum of white LED lights and propose low-cost filters to reduce the blue-rich components of LED lighting.
关键词： Domestic Lighting,Rural Context,Light-Emitting Diode
更新于2025-09-23 15:21:01
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Conditioned media from blue light-emitting diodea??exposed fibroblasts have an anti-inflammatory effect in vitro
摘要： We have previously reported the protective effects of blue light-emitting diode (BLED)–stimulated cell metabolites on cell injury. To further examine the effect of conditioned media (CM) derived from BLED (5 J/cm2)-exposed human normal fibroblasts (CMBL5) for clinical application, we have used the choline chloride and phenol red–free media and then concentrated CMBL5 using a centrifugal filter unit. The collected CMBL5-lower part (CMBL5-LO) has evaluated the inflammatory protein expression profile in LPS-stimulated RAW264.7 cells. Comprehensive metabolomic profiling of CMBL5-LO was carried out using hybrid tandem mass spectrometry. Treatment with CMBL5-LO showed the cytoprotective effect on apoptotic cell death, but rather increased apoptotic cells after treatment with CMBL5-upper part (CMBL5-UP). In addition, CMBL5-LO inhibited several chemo-attractants, including interleukin (IL)-6, macrophage inflammatory protein (MIP)-2, chemokine (C-C motif) ligand 5 (CCL5), granulocyte colony-stimulating factor (GCSF), and monocyte chemoattractant protein-1 (MCP-1) expression. Pro-inflammatory nitric oxide was decreased after CMBL5-LO treatment, but not by CMBL5-UP treatment. Interestingly, treatment with CMBL5-LO stimulated expression of heme oxygenase-1, indicating its anti-inflammatory property. Most endoplasmic reticulum (ER) stress proteins except for transcription factor C/EBP homologous protein (CHOP) were highly expressed after irradiation with BLED in cells. Further studies are needed to examine the precise mechanism by CMBL5-LO in cells.
关键词： Inflammation,CMBL5-LO,Light-emitting diode,ER stress
更新于2025-09-23 15:21:01
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CsPbBr3 nanowire polarized light-emitting diodes through mechanical rubbing
摘要： Anisotropic films composed of aligned CsPbBr3 nanowires (NWs) have been successfully fabricated using a mechanical rubbing method. The films with dense and uniform morphology show polarization photoluminescence (PL) behavior. Combining with an optimal device structure, a polarized light-emitting diode (LED) with a turn-on voltage as low as 6.5 V was achieved.
关键词： CsPbBr3 nanowires,anisotropic films,mechanical rubbing,polarized light-emitting diode,photoluminescence
更新于2025-09-23 15:21:01