研究目的
Investigating the effects of Sn ion density on the chemical, structural, and optical properties of CdTe:Sn thin films deposited by pulsed laser deposition.
研究成果
Substitutional incorporation of Sn into a CdTe matrix was successfully achieved by the combination of Sn and CdTe plasmas in a PLD process. The Sn content in the films was varied from 0.1 to 0.5 at. % due to the Sn plasma density variation which can be controlled by means of Langmuir planar probe measurements. The appearance of a Raman vibrational mode centered at 118 cm-1 was related to the substitutional incorporation of Sn into the CdTe lattice and associated to the A1 Sn-Te vibration. The calculated band gap for the CdTe and CdTe:Sn films was around 1.43 eV. A preferential orientation on the (110) direction was induced by the incorporation of Sn into the hexagonal CdTe structure.
研究不足
The study is limited to the effects of Sn ion density on the properties of CdTe:Sn thin films and does not explore other doping elements or deposition conditions.
1:Experimental Design and Method Selection
CdTe:Sn thin films were grown by pulsed laser deposition on glass substrates at room temperature. The Sn ion density was modified by varying the fluence on the Sn target, while the CdTe plasma density was kept constant for all the deposits.
2:Sample Selection and Data Sources
Four films were grown by the simultaneous ablation of CdTe and Sn targets in vacuum. The chemical composition was analyzed by XPS, and the crystalline structure was analyzed by XRD.
3:List of Experimental Equipment and Materials
A Nd:YAG laser with 600 mJ of maximum output energy, at a wavelength of 1064 nm, 6 ns pulse width, and repetition rate of 10 Hz was used. A 6 mm diameter planar Langmuir probe biased at -48 V was used for plasma measurements.
4:Experimental Procedures and Operational Workflow
The beam was divided into two equal beams using a beam splitter. One beam was focused on each target while they were rotating at 15 rpm to avoid drilling. Depositions were carried out in vacuum at a pressure of 6 × 10-5 Torr and 10 minutes of ablation time.
5:Data Analysis Methods
The chemical composition was analyzed by XPS, the crystalline structure by XRD, and vibrational behavior by Raman spectroscopy. The band gap was calculated using UV-Vis spectrophotometry.
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