研究目的
Investigating the composition and poling-dependent photovoltaic studies in ferroelectric (Bi1?xSrx)(Fe1?xTix)O3 thin films.
研究成果
The study demonstrated a correlation between the structural phase evolution, polarization, and photovoltaic response in (Bi1?xSrx)(Fe1?xTix)O3 thin films. The dominant role of polarization over the interface Schottky effect in the photovoltaic response was elucidated. This work contributes to the understanding of ferroelectric photovoltaic mechanisms and may guide the design of optimized photovoltaic materials.
研究不足
The study is limited to the specific compositions of (Bi1?xSrx)(Fe1?xTix)O3 thin films and their photovoltaic properties under certain conditions. The mechanisms behind the observed photovoltaic effects are not fully understood and require further investigation.
1:Experimental Design and Method Selection:
The study involved the growth of polycrystalline (Bi1?xSrx)(Fe1?xTix)O3 thin films on Pt(111)/TiO2/SiO2/Si(100) substrates using chemical solution deposition technique. X-ray diffraction and Raman spectroscopy were used to analyze the structural properties. Photovoltaic measurements were conducted to study the photovoltaic response.
2:Sample Selection and Data Sources:
Samples with x = 0.0, 0.05, 0.10, and 0.20 were prepared. Data were collected from X-ray diffraction patterns, Raman spectra, and photovoltaic measurements.
3:0, 05, 10, and 20 were prepared. Data were collected from X-ray diffraction patterns, Raman spectra, and photovoltaic measurements. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Rigaku smart lab X-ray spectrometer, Horiba LabRam spectroscopic instrument, Bentham PVE 300 diffused reflectance spectroscopy (DRS), Radiant Technology PMF0713-334 polarization loop tracer, piezo-response force microscopy (PFM) (Park system NX10), Keithley’s high resistance electrometer (6517B), Xenon arc lamp.
4:Experimental Procedures and Operational Workflow:
Thin films were grown, characterized by X-ray diffraction and Raman spectroscopy, and their photovoltaic properties were measured under various poling conditions.
5:Data Analysis Methods:
The data were analyzed to correlate the structural phase evolution and polarization with the photovoltaic response.
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High resistance electrometer
Keithley 6517B
Keithley
Trace the photovoltaic response of the thin films
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X-ray spectrometer
Rigaku smart lab
Rigaku
Phase analysis of the films
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Polarization loop tracer
Radiant Technology PMF0713-334
Radiant Technology
Record the ferroelectric characteristics of the samples
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Raman spectroscopic instrument
Horiba LabRam
Horiba
Confirm the structural phase of the prepared films
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Diffused reflectance spectroscopy
Bentham PVE 300
Bentham
Measure the optical bandgap of the films
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Piezo-response force microscopy
Park system NX10
Park system
Measure the ferroelectric characteristics at the local level
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Xenon arc lamp
Serve as a light source for photovoltaic measurements
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