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Expanding the Light-Harvesting of CsPbI2Br to Near-Infrared by Integrating with Organic Bulk-Heterojunction for Efficient and Stable Solar Cells

DOI:10.1021/acsami.9b14957 期刊:ACS Applied Materials & Interfaces 出版年份:2019 更新时间:2025-09-12 10:27:22
摘要: All-inorganic perovskite (CsPbX3, X=Br or I) solar cells demonstrate superior stability while the power conversion efficiency (PCE) lags behind the organic-inorganic hybrid counterparts mainly due to the limitation of narrow absorption bands. To broaden its absorption spectrum and improve its PCE, all-inorganic perovskite/organic integrated solar cells utilizing CsPbI2Br as ultraviolet-visible light absorber and PBDTTT-E-T:IEICO as near-infrared light absorber are demonstrated in this work. The integrated solar cells exhibit a broadened photo-response to over 900 nm attributing to the integration of PBDTTT-E-T:IEICO. The additional absorption enhances the short-circuit current density from 14.78 mA/cm2 to 15.98 mA/cm2, resulting greatly improved PCE of 14.03% for integrated solar cells, much higher than that of the control perovskite solar cells (12.53%) and organic solar cells (7.51%). In-depth understanding of the charge transfer dynamic process in CsPbI2Br/PBDTTT-E-T:IEICO film is comprehensively analyzed by photoinduced transient absorption spectroscopy. Furthermore, the air stability and thermal stability of the integrated solar cells are greatly enhanced. For unencapsulated integrated solar cells, the PCE still preserve 95% of its initial value after aging for 300 hours in an ambient environment and the PCE retains about 90% of its original value even after aged at 85 ℃ for 180 hours in nitrogen.
作者: Qiang Guo,Yiming Bai,Kun Lang,Zhongzhen Yu,Tasawar Hayat,Ahmed Alsaedi,Erjun Zhou,Zhan'ao Tan
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To broaden the absorption spectrum and improve the power conversion efficiency (PCE) of all-inorganic perovskite solar cells by integrating CsPbI2Br with PBDTTT-E-T:IEICO to harvest more photons.

The integration of CsPbI2Br with PBDTTT-E-T:IEICO successfully broadened the photo-response of the solar cells to over 900 nm and improved the PCE to 14.03%. The study also demonstrated enhanced air and thermal stability of the integrated solar cells, making them a promising approach for improving the efficiency and stability of all-inorganic perovskite solar cells.

The study focuses on the integration of CsPbI2Br with PBDTTT-E-T:IEICO for solar cells, which may have limitations in terms of scalability, cost, and compatibility with existing solar cell technologies. The stability tests were conducted under specific conditions (ambient environment and nitrogen atmosphere at 85℃), which may not cover all real-world operating conditions.

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