研究目的
To broaden the absorption spectrum and improve the power conversion efficiency (PCE) of all-inorganic perovskite solar cells by integrating CsPbI2Br with PBDTTT-E-T:IEICO to harvest more photons.
研究成果
The integration of CsPbI2Br with PBDTTT-E-T:IEICO successfully broadened the photo-response of the solar cells to over 900 nm and improved the PCE to 14.03%. The study also demonstrated enhanced air and thermal stability of the integrated solar cells, making them a promising approach for improving the efficiency and stability of all-inorganic perovskite solar cells.
研究不足
The study focuses on the integration of CsPbI2Br with PBDTTT-E-T:IEICO for solar cells, which may have limitations in terms of scalability, cost, and compatibility with existing solar cell technologies. The stability tests were conducted under specific conditions (ambient environment and nitrogen atmosphere at 85℃), which may not cover all real-world operating conditions.
1:Experimental Design and Method Selection:
The study utilized CsPbI2Br as ultraviolet-visible light absorber and PBDTTT-E-T:IEICO as near-infrared light absorber to construct integrated solar cells.
2:Sample Selection and Data Sources:
The samples were prepared using specific materials and methods, including the fabrication of solar cells with different active layers.
3:List of Experimental Equipment and Materials:
Materials included Tin (IV) oxide, ultra-dry chlorobenzene, 1,8-diiodooctane (DIO), N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), PbI2, CsBr, spiro-OMeTAD, 4-tert-Butylpyridine (tBP), PBDTTT-E-T, and IEICO. Equipment included Shimadzu UV-2450 for UV-Vis absorption spectra, FluoroLog-3 Modular Spectrofluorometer for PL measurements, PHAROS HIRO HARPIA femtosecond transient absorption system for TA spectroscopy, Agilent 5500 atomic force microscope (AFM) for surface topography, and Keithley 2400 digital source meter for J-V characterization.
4:Experimental Procedures and Operational Workflow:
The fabrication process involved spin-coating, annealing, and evaporation techniques to prepare the solar cells.
5:Data Analysis Methods:
The performance of the solar cells was analyzed through J-V characterization, EQE measurements, and stability tests.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容