研究目的
To develop a high-performance, repeatable and low-cost humidity sensor based on indium oxide quantum dots (In2O3 QDs) for accurate and real-time monitoring of humidity.
研究成果
The QCM humidity sensor based on In2O3 QDs exhibits outstanding sensitivity, fast response/recovery times, and good stability for humidity detection. It shows potential for practical applications in daily life, such as monitoring human breath.
研究不足
The study focuses on the humidity sensing performance at room temperature and does not explore the effects of temperature variations on sensor performance. The long-term stability beyond 30 days was not investigated.
1:Experimental Design and Method Selection:
The In2O3 QDs were synthesized via a solvothermal method and spin-coated onto QCM devices. An annealing process was applied to remove organic long chains and expose more moisture adsorption sites.
2:Sample Selection and Data Sources:
QCM devices with a resonant frequency of 8 MHz were used. In2O3 QD films were prepared with different deposition repeat cycles (2, 4, 6 times).
3:List of Experimental Equipment and Materials:
QCM devices, indium acetate, oleic acid (OA), oleylamine (OLA), ethanol, toluene, saturated solutions of LiCl, MgCl2, K2CO3, NaBr, NaCl, and KCl for humidity environments.
4:Experimental Procedures and Operational Workflow:
In2O3 QDs were synthesized, spin-coated onto QCM devices, and annealed. Humidity sensing performance was characterized at room temperature.
5:Data Analysis Methods:
The mass of the In2O3 QDs deposited on the electrode of QCMs was calculated using the Sauerbrey equation. The humidity sensitivity was quantified by measuring changes of resonance frequency.
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MAXima XXRD-7000
XXRD-7000
Shimadzu
Used for X-ray diffraction (XRD) analysis of the QD films.
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PerkinElmer Lambda 950
Lambda 950
PerkinElmer
Used to measure the optical absorption spectra of the QDs.
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Zeiss Supra 55
Supra 55
Zeiss
Used for surface morphologies characterization of the QD samples.
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JEOL-2100
2100
JEOL
Used for high-resolution transmission electron microscopy (HR-TEM) of the QD samples.
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VERTEX 70
70
Bruker
Used for Fourier transform infrared (FTIR) spectroscopy of the QD samples.
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QCM device
8 MHz
Wuhan Hi-Trusty Electronics Co., Ltd.
Used as the base for the humidity sensor, to measure the mass change caused by water molecules.
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