研究目的
To develop stable and efficient CsPbI2Br perovskite solar cells through a europium and acetate co-doping strategy, addressing the issues of low efficiency and moisture instability in all-inorganic perovskite solar cells.
研究成果
The europium and acetate co-doping strategy significantly improves the crystallinity, electrical, and optical properties of CsPbI2Br perovskite films, leading to high-efficiency and stable perovskite solar cells. The champion device achieved a PCE of 15.25% and maintained over 80% of its initial efficiency after 30 days in air.
研究不足
The study focuses on the doping of Eu(Ac)3 in CsPbI2Br perovskite solar cells, and while it shows improved efficiency and stability, the long-term stability under various environmental conditions beyond 30 days and the scalability of the fabrication process are not addressed.
1:Experimental Design and Method Selection:
The study introduced Eu3+ to partly substitute Pb2+ in the CsPbI2Br perovskite structure and functionalized Ac? to obtain high-quality inorganic perovskite films.
2:Sample Selection and Data Sources:
CsPbI2Br perovskite films were prepared with different concentrations of Eu(Ac)3 dopant.
3:List of Experimental Equipment and Materials:
Materials included PbI2(DMSO)2 adducts, CsI, PbBr2(DMSO)2, and Europium acetate (Eu(Ac)3). Equipment included XRD, UV–vis spectrophotometer, PL and TRPL spectrometers, SEM, TEM, EDX, XPS, and solar simulator for J–V curves.
4:3). Equipment included XRD, UV–vis spectrophotometer, PL and TRPL spectrometers, SEM, TEM, EDX, XPS, and solar simulator for J–V curves. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: The CsPbI2Br perovskite films were fabricated on TiO2-coated FTO substrates, followed by the deposition of Spiro-OMeTAD and Au layers.
5:Data Analysis Methods:
The performance of the solar cells was analyzed through J–V curves, EQE measurements, and stability tests.
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FLS980 spectrometer
FLS980
Edinburgh Instruments Ltd
Measuring PL spectra.
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PicoQuant FluoQuant 300
FluoQuant 300
PicoQuant
Measuring TRPL spectra.
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Field-emission scanning electron microscopy
SU-8020
HITACHI
Obtaining top-view images of perovskite films and cross-sectional images of inorganic PSCs.
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Photoelectron spectrometer
ESCALAB250Xi
Thermo Fisher Scientific
Carrying out XPS of the inorganic perovskite films.
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Keithley 2400 source
2400
Keithley
Performing J–V curves of the inorganic PSCs under the illumination of an AM 1.5G at 100 mW cm?2 irradiance.
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D/MAX 2400 diffractometer
D/MAX 2400
Rigaku
Performing XRD patterns to identify the change of perovskite crystal structure.
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UV–vis NIR spectrophotometer
Lambda 950
PerkinElmer
Measuring the absorption spectra of perovskite films.
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SAN-EIELECTRIC XES-40S2-CE solar simulator
XES-40S2-CE
SAN-EIELECTRIC
Generating AM 1.5G at 100 mW cm?2 irradiance for J–V curves.
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QTest Station 2000ADI system
2000ADI
Crowntech Inc.
Recording the external quantum efficiency (EQE) of the inorganic PSCs.
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