研究目的
Investigating the synthesis and application of dual-mode light-emitting lanthanide metal-organic frameworks (Ln-MOFs) with high water and thermal stability in white LEDs.
研究成果
The synthesized Ln-MOFs exhibit dual-mode luminescence, high thermal and water stability, and potential applications in white LEDs. The symmetry around Eu3+ ions in Eu-MOF is the highest, and the material shows promise for achieving white light with excellent color quality and vision performance.
研究不足
The study focuses on the synthesis and luminescent properties of Ln-MOFs, with potential limitations in scalability and practical application in commercial LEDs.
1:Experimental Design and Method Selection:
Ln-MOFs were synthesized using a low-cost hydrothermal method with LnCl3·6H2O, H3BTC, DMF, and deionized water.
2:Sample Selection and Data Sources:
Samples were characterized by XRD, SEM, TEM, FTIR, Raman, TGA, and PL spectra.
3:List of Experimental Equipment and Materials:
Bruker D8 Advance Diffractometer, Hitachi S-4800 SEM, JEM 2010 TEM, Perkin-Elmer Spectrum One FTIR spectrometer, Jobin Yvon HR 800 micro-Raman spectrometer, TGA-7 thermal analyzer, Hitachi F-4600 fluorescence spectrophotometer.
4:Experimental Procedures and Operational Workflow:
Samples were prepared at 60°C for 24 h, washed with DMF and ethanol, and dried at ~60 °C for 6 h.
5:Data Analysis Methods:
J-O parameters were calculated from emission spectra, and color characteristics of white light were calculated using combined spectral power distributions.
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Perkin-Elmer Spectrum One FTIR spectrometer
Spectrum One
Perkin-Elmer
Measuring Fourier-transform infrared spectra of the samples.
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TGA-7 thermal analyzer
TGA-7
Perkin-Elmer
Performing thermogravimetry measurements.
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Hitachi F-4600 fluorescence spectrophotometer
F-4600
Hitachi
Measuring the PL spectra.
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Bruker D8 Advance Diffractometer
D8 Advance
Bruker
Analyzing the crystal structure of samples by measuring X-ray diffraction patterns.
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Hitachi S-4800 SEM
S-4800
Hitachi
Measuring the morphology of the samples.
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JEM 2010 TEM
2010
JEM
Measuring the morphology of the samples.
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Jobin Yvon HR 800 micro-Raman spectrometer
HR 800
Jobin Yvon
Performing Raman measurements.
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