研究目的
Investigating the voltage-dependencies in the external quantum efficiency (EQE) spectra of ultrathin GaAs solar cells and their implications for the use of the reciprocity relation between photovoltaic quantum efficiency and electroluminescence.
研究成果
The Franz-Keldysh effect significantly impacts the EQE spectra of ultrathin GaAs solar cells, especially in cells with a textured rear mirror. This effect must be considered when using the reciprocity relation between photovoltaic quantum efficiency and electroluminescence to avoid underestimating the radiative limit for the open-circuit voltage.
研究不足
The study focuses on ultrathin GaAs solar cells, and the findings may not be directly applicable to thicker cells or cells made from other materials. The impact of the Franz-Keldysh effect is more pronounced in cells with specific structures, such as those with a textured rear mirror.
1:Experimental Design and Method Selection:
The study involved measuring the EQE spectra of ultrathin GaAs solar cells under various bias voltages and using optical simulations to analyze the Franz-Keldysh effect.
2:Sample Selection and Data Sources:
Ultrathin GaAs solar cells with different emitter doping levels and structures (including cells with a textured rear mirror) were used.
3:List of Experimental Equipment and Materials:
A ReRa SpeQuest system for EQE measurements, a solar simulator for JV-characteristics, and a transfer-matrix method for optical simulations.
4:Experimental Procedures and Operational Workflow:
EQE measurements were made at different bias voltages, and the data were analyzed to observe the Franz-Keldysh effect.
5:Data Analysis Methods:
The EQE data were analyzed to determine the impact of the Franz-Keldysh effect on the solar cells' performance.
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