研究目的
Investigating the advantages and drawbacks of disilane for the low temperature growth of Si and SiGe in 300 mm Reduced Pressure – Chemical Vapour Deposition chambers.
研究成果
Disilane provides significantly higher growth rates for Si and SiGe at low temperatures compared to silane and dichlorosilane. The study also found that in-situ surface preparation processes result in lower interfacial contamination and smoother epitaxial surfaces compared to ex-situ 'HF-Last' wet cleanings.
研究不足
The study is limited to the comparison of two specific RP-CVD chambers and does not explore the full range of possible chamber geometries or conditions. The focus on low temperature growth may not be applicable to higher temperature processes.
1:Experimental Design and Method Selection:
The study assessed the growth of Si and SiGe using disilane, silane, and dichlorosilane in RP-CVD chambers from two major suppliers.
2:Sample Selection and Data Sources:
300 mm bulk Si(001) wafers were used as substrates. Growth rates and Ge concentrations were measured using X-Ray Reflectivity and X-Ray Diffraction.
3:List of Experimental Equipment and Materials:
RP-CVD chambers from two suppliers, XRR and XRD tools for measurement.
4:Experimental Procedures and Operational Workflow:
Growth was performed at 20 Torr with varying temperatures and precursor mass-flow ratios.
5:Data Analysis Methods:
Growth rates and Ge concentrations were analyzed to compare the effectiveness of different precursors and chamber geometries.
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