研究目的
Investigating the solvothermal synthesis, crystal structure, and luminescent properties of a novel two-dimensional Zn(II) metal-organic framework built from a tetrazole ligand.
研究成果
The study successfully synthesized a novel structural metal-organic framework with good luminescent properties, suggesting potential applications in various fields. The compound's structure was characterized, and its luminescent properties were investigated, indicating ligand-to-metal-charge-transfer (LMCT) as the emission mechanism.
研究不足
The study focuses on the synthesis and characterization of a specific metal-organic framework. The potential applications in lighting, displays, or biomedicine are suggested but not extensively explored.
1：Experimental Design and Method Selection:
The study employed solvothermal synthesis to prepare the metal-organic framework. Single-crystal X-ray diffraction was used for structural characterization.
2：Sample Selection and Data Sources:
The compound was synthesized from Zn(NO3)2·6H2O, 1,4-dimethylpiperazine, 5-amino-1H-tetrazole (ATZ), 1,4-benzenedicarboxylate (H2bdc), tetramethylammonium bromide, 3-amino-1-propanol, methanol, and N,N-dimethylacetamide (DMA).
3：List of Experimental Equipment and Materials:
NETSCHZ STA-449C simultaneous TG-DSC thermoanalyzer, MiniFlex-II diffractometer, XCalibur E CCD diffractometer.
4：Experimental Procedures and Operational Workflow:
The mixture was heated at 100 °C for 72 h, then cooled to room temperature. Crystals were washed with acetone and dried.
5：Data Analysis Methods:
The structures were solved using the direct method and refined by full-matrix least-squares methods on F2 using the SHELX-97 program package.
独家科研数据包，助您复现前沿成果，加速创新突破
获取完整内容
