研究目的
Investigating the electronic spectrum of metal complexes to determine their geometry and understand the underlying concepts of symmetry, term symbols, and selection rules.
研究成果
The electronic spectroscopy of transition metal complexes provides valuable information about their geometry and electronic structure. Understanding the symmetry properties and selection rules is crucial for interpreting the spectra. The study highlights the importance of term symbols, group theory, and the direct product concept in predicting and assigning transitions. The limitations of qualitative methods like the Orgel diagram are addressed by the use of Tanabe-Sugano diagrams for more accurate quantitative analysis.
研究不足
The Orgel diagram is only qualitative and applies to only weak-field cases. The interpretation of spectra is more complex for strong-field cases and requires Tanabe-Sugano diagrams for quantitative analysis.
