研究目的
Investigating the optical optimization of a multi-layer wideband anti-reflection coating using porous MgF2 for sub-micron-thick CIGS solar cells to reduce optical losses and improve photo-current density.
研究成果
The study successfully optimized a porous-on-compact double-layer anti-reflection coating based on MgF2 for a CIGS solar cell with an absorber thickness of 750 nm. The proposed ARC structure effectively reduces reflectance to values below 5% in a wide wavelength range, leading to a 6.77% increase in implied photocurrent density. The combination of the double-layer ARC with a point-contacted double-layer dielectric spacer improved the long wavelength performance of the solar cell, resulting in an 11.3% improvement in Jph.
研究不足
The model is valid for lab-scale CIGS solar cells without encapsulating layers. In case of encapsulation, further optimizations are needed. The fabrication process of porous MgF2-based films requires high temperatures, which may degrade the CdS buffer layer in standard CIGS solar cell structures.
1:Experimental Design and Method Selection:
3-D optical modelling was used to optimize light in-coupling and internal rear reflectance in a 750-nm thick CIGS reference solar cell. An effective medium approximation (EMA) approach was applied for describing optical properties of a MgF2-based anti-reflection coating (ARC).
2:Sample Selection and Data Sources:
A 750-nm thick CIGS reference solar cell was used as the sample. The optical properties of MgF2 were taken from literature.
3:List of Experimental Equipment and Materials:
Ansoft HFSS, a 3D Maxwell's equation solver based on finite element method (FEM), was used for modelling.
4:Experimental Procedures and Operational Workflow:
Sequential nonlinear programming (SNLP) algorithm was selected to find the optimal values of the ARC parameters. The optimization goal was set to R(λ) ≤ 0.05 for wavelengths between 300 and 800 nm.
5:05 for wavelengths between 300 and 800 nm.
Data Analysis Methods:
5. Data Analysis Methods: The EQE and 1-R spectra were analyzed to evaluate the performance of the solar cell with and without the optimized ARC.
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