研究目的
Modeling the temperature dependent material dispersion of imidazolium based ionic liquids in the Vis-NIR.
研究成果
The refractive index of imidazolium based ionic liquids was successfully modeled using a single resonance Sellmeier dispersion formula, showing that the resonance's position is independent of temperature while its strength varies linearly. This model accurately reproduces experimental data and allows for the calculation of the thermo-optic coefficient and its wavelength dependence. The study provides valuable insights into the optical properties of ionic liquids, which are essential for their application in optoelectronics and photonics.
研究不足
The study is limited to imidazolium based ionic liquids with three specific anions (BF4, NTf2, OTf) and a temperature range from 298.15 K to 323.15 K. The model assumes a single UV resonance which may not capture all dispersion characteristics for other types of ionic liquids or broader temperature ranges.
1:Experimental Design and Method Selection:
The refractive indices of eleven 1-alkyl-3-methylimidazolium based ionic liquids were measured using an Abbe refractometer and white light spectral interferometry (WLSI) in the temperature interval from
2:15 K to 15 K and wavelength range from 400 to 1000 nm. Sample Selection and Data Sources:
2 All compounds were supplied by IoLiTec, dried, and kept in glass vials to prevent contact with air moisture.
3:List of Experimental Equipment and Materials:
Anton Paar DSA-5000M vibrating tube density and sound velocity meter, Abbe refractometer Atago DR-M2, white light source, Michelson interferometer, spectrometer, quartz cell Hellma 100-QS 1 mm.
4:Experimental Procedures and Operational Workflow:
Refractive indices were measured at the sodium D line using the Abbe refractometer and dispersion was obtained using WLSI. The phase difference between beams was extracted from the interferogram.
5:Data Analysis Methods:
The refractive index squared was modeled using a single resonance Sellmeier dispersion formula to analyze the dependence on wavelength and temperature.
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