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Strain-engineering of twist-angle in graphene/hBN superlattice devices

DOI:10.1021/acs.nanolett.8b03854 期刊:Nano Letters 出版年份:2018 更新时间:2025-09-09 09:28:46
摘要: The observation of novel physical phenomena such as Hofstadter’s butterfly, topological currents and unconventional superconductivity in graphene have been enabled by the replacement of SiO2 with hexagonal Boron Nitride (hBN) as a substrate and by the ability to form superlattices in graphene/hBN heterostructures. These devices are commonly made by etching the graphene into a Hall-bar shape with metal contacts. The deposition of metal electrodes, the design and specific configuration of contacts can have profound effects on the electronic properties of the devices possibly even affecting the alignment of graphene/hBN superlattices. In this work we probe the strain configuration of graphene on hBN contacted with two types of metal contacts, two-dimensional (2D) top-contacts and one-dimensional (1D) edge-contacts. We show that top-contacts induce strain in the graphene layer along two opposing leads, leading to a complex strain pattern across the device channel. Edge-contacts, on the contrary, do not show such strain pattern. A finite-elements modelling simulation is used to confirm that the observed strain pattern is generated by the mechanical action of the metal contacts clamped to the graphene. Thermal annealing is shown to reduce the overall doping whilst increasing the overall strain, indicating and increased interaction between graphene and hBN. Surprisingly, we find that the two contacts configurations lead to different twist-angles in graphene/hBN superlattices, which converge to the same value after thermal annealing. This observation confirms the self-locking mechanism of graphene/hBN superlattices also in the presence of strain gradients. Our experiments may have profound implications in the development of future electronic devices based on heterostructures and provide a new mechanism to induce complex strain patterns in 2D materials.
作者: Adolfo De Sanctis,Jake D. Mehew,Saad Alkhalifa,Freddie Withers,Monica Felicia Craciun,Saverio Russo
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To study the effect of strain induced by metal contacts in graphene/hBN superlattice devices and to compare the strain patterns induced by two-dimensional (2D) top-contacts and one-dimensional (1D) edge-contacts.

Top-contacts induce strain in graphene along two opposing leads, creating a complex strain pattern, while edge-contacts do not. Thermal annealing reduces doping and increases compressive strain, leading to a convergence of twist-angles in graphene/hBN superlattices for both contact types. This confirms the self-locking mechanism of graphene/hBN superlattices even in the presence of strain gradients.

The study is limited to semi-encapsulated graphene/hBN devices without a top hBN layer, which may affect the strain and doping levels compared to fully encapsulated devices. The resolution of the experimental technique for strain measurement is approximately 0.005%.

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