研究目的
Investigating the photoluminescent and structural properties of trivalent europium doped SrGdAlO4 nanophosphors for potential applications in warm white light and phosphor converted white light emitting diodes (Pc-WLEDs).
研究成果
The synthesized Eu3+ doped SrGdAlO4 nanophosphors exhibit color tunability and potential applications in warm white light and Pc-WLEDs. The optical band gap values indicate semiconductor properties, expanding their application areas.
研究不足
The study is limited to the synthesis and characterization of Eu3+ doped SrGdAlO4 nanophosphors via solution combustion technique. The optimal doping concentration was found to be 20 mol%, beyond which concentration quenching occurs.
1:Experimental Design and Method Selection
Solution combustion technique utilizing urea as a fuel was employed for the synthesis of Eu3+ ion doped SrGdAlO4 nanophosphors. Structural and photoluminescent properties were characterized using powder X-ray diffraction (PXRD), photoluminescence spectra, decay curves, UV–Visible diffuse reflectance spectra (UV–Vis DRS), and Judd–Ofelt analysis.
2:Sample Selection and Data Sources
Analytical grade chemicals including Sr(NO3)2, Gd(NO3)3·6H2O, Eu(NO3)3·5H2O, Al(NO3)3·9H2O, and urea were used as starting materials. The samples were sintered at various temperatures for characterization.
3:List of Experimental Equipment and Materials
High precision X-ray Rigaku Ultima-IV diffractometer, Hitachi F-7000 fluorescence spectrophotometer, Shimadzu UV-3600 Plus UV–Vis-NIR Spectrophotometer.
4:Experimental Procedures and Operational Workflow
The raw materials were dissolved in deionized water and heated in a furnace at 500°C. The resulting powder was sintered at different temperatures, cooled, and characterized.
5:Data Analysis Methods
Judd–Ofelt analysis was used to estimate radiative rates, branching ratios, and intensity parameters. CIE coordinates and CCT values were calculated using MATLAB program and McCamy’s equation, respectively.
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