摘要： β-Ga2O3 has recently emerged as a novel wide-bandgap semiconductor with immense potential for applications in power electronics and optoelectronics. Experimental advancements in the past 5 years have been significant toward realizing commercial β-Ga2O3 devices in the near future [1–7]. Matured crystal growth and processing techniques make the material further promising [8–10]. In terms of power electronic applications, MOSFETs based on this material have been demonstrated that could withstand record high voltages [11, 12]. The accuracy of n-type doping and the difficulty of p-type doping make electrons the primary charge carriers in β-Ga2O3. Although β-Ga2O3 has lower electron mobility compared to other wide-bandgap semiconductors, it is found to have a superior Baliga’s figure of merit that jointly accounts for on-state resistance and breakdown voltage [4]. So it is important to investigate in rigor the fundamentals behind β-Ga2O3 material properties that could be beneficial to gain an understanding on the causes that control mobility and breakdown voltage. There are theoretical reports on fundamental materials aspects including electronic structure [13] and optical properties [14], lattice dynamical and dielectric properties [15], and thermal properties [16, 17] as well. The primary physics behind both mobility (and hence the device on resistance) and breakdown voltage lies in the electron transport phenomenon. There have been a few experimental reports that try to characterize the electron transport and scattering mechanisms in β-Ga2O3 with Hall measurements being reported a few times to predict temperature dependence and also crystal orientation dependence of the electron mobility [18, 19]. On the other hand, we are making a systemic study on the theoretical understanding of electron transport in β-Ga2O3 starting from the first principles [20–22]. The main idea is to follow a bottom-up approach in order to develop an understanding of the near-equilibrium and far-from-equilibrium electron dynamics in β-Ga2O3. This is unique compared to conventional semiconductors in a way that β-Ga2O3 has a low-symmetry crystal structure and a fairly large primitive unit cell that gives rise to many phonon modes. On several occasions, the traditional notions of electron transport that are applicable to Si and GaAs actually do not quite hold well in the case of β-Ga2O3. In this chapter, we attempt to provide a comprehensive picture of electron transport in β-Ga2O3 under low and moderately high electric fields based on our work in the recent years.