研究目的
To improve the performance of VO2-based thermochromic coatings for smart window applications by combining four methods: low-temperature deposition, doping with W, using ZrO2 antireflection layers, and optimizing the design to enhance both luminous transmittance and solar transmittance modulation.
研究成果
The study successfully demonstrated the improvement of VO2-based thermochromic coatings through low-temperature deposition, W doping, and the use of ZrO2 antireflection layers. The second-order interference design optimized both luminous transmittance and solar transmittance modulation, making the coatings suitable for smart window applications.
研究不足
The study focuses on the optimization of ZrO2/V1-xWxO2/ZrO2 coatings for smart window applications, with specific attention to low-temperature fabrication and performance enhancement. Potential areas for optimization include further reduction of deposition temperature and exploration of alternative antireflection materials.
1:Experimental Design and Method Selection:
The coatings were prepared by reactive magnetron sputtering, combining high-power impulse magnetron sputtering (HiPIMS) for VO2 deposition and dual reactive sine-wave mid-frequency ac magnetron sputtering for ZrO2 layers.
2:Sample Selection and Data Sources:
Soda-lime glass substrates were used. The properties of pure ZrO2 and V1-xWxO2 were obtained from preliminary depositions.
3:List of Experimental Equipment and Materials:
Ultra-high vacuum multi-magnetron sputter device, high-power pulsed dc power supply, asymmetric pulsed dc power supply, mid-frequency ac power supply, X-ray diffractometer, spectrophotometer, spectroscopic ellipsometer.
4:Experimental Procedures and Operational Workflow:
Deposition of bottom ZrO2 layer, middle V1-xWxO2 layer, and top ZrO2 layer at controlled temperatures and pressures. Characterization by XRD, spectrophotometry, and ellipsometry.
5:Data Analysis Methods:
Optical data fitting and transmittance prediction using WVASE software, calculation of luminous and solar transmittance.
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