研究目的
Investigating the impact of gate dielectric interfaces on trap states and cumulative charge in high-performance organic thin film transistors.
研究成果
High-performance low-voltage OFETs were achieved with solution-processed ZrO2 gate dielectrics modified by PMMA, showing improved mobility, threshold voltage, on/off ratio, and subthreshold slope due to reduced interface roughness and trap states. Thinner films provide stronger coupling and more cumulative charge, optimizing device performance.
研究不足
The capacitance was measured at 100 Hz, which may underestimate values and overestimate mobility; experimental funds and personnel restrictions limited further measurements.
1:Experimental Design and Method Selection:
Fabrication of p-channel pentacene OFETs with solution-processed ZrO2 gate dielectric at low temperature, modified with polymers (PMMA or PS) to study interface properties. Use of AFM, XRR, and electrical measurements to characterize morphology, thickness, and performance.
2:Sample Selection and Data Sources:
Si substrates cleaned and used for device fabrication. Precursor solutions prepared with zirconium(IV) isopropoxide isopropanol complex, acetylacetone, nitric acid, PMMA, PS, and solvents like anisole and toluene.
3:List of Experimental Equipment and Materials:
Spin coater for deposition, hot plate for annealing, UV light for curing, thermal evaporator for electrode deposition, Keithley 4200-SCS for electrical measurements, AFM for morphology, XRR for thickness, capacitance meter (4294 A) for capacitance-frequency characteristics.
4:Experimental Procedures and Operational Workflow:
Clean substrates, spin-coat ZrO2 layers, anneal, UV cure, spin-coat polymer modification layers, evaporate pentacene and Au electrodes, measure electrical properties and capacitance.
5:Data Analysis Methods:
Use equations for mobility, subthreshold slope, trap density calculation; statistical analysis of device parameters.
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Keithley 4200-SCS
4200-SCS
Keithley
Electrical properties measurement of OFETs under ambient conditions.
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Atomic Force Microscope
Characterize morphology of dielectric and pentacene films.
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X-ray Reflectivity
Measure thickness of the insulator.
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Capacitance Meter
4294 A
Santa Clara
Measure capacitance-frequency characteristics of MIM structures.
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Spin Coater
Deposit ZrO2 and polymer layers by spin-coating.
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Hot Plate
Annealing of deposited layers.
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Thermal Evaporator
Evaporate pentacene and Au electrodes.
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PTFE Syringe Filter
0.2 μm
Filter precursor solutions before spin coating.
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