研究目的
Investigating the effective light polarization insensitive and omnidirectional properties of Si nanowire arrays developed on different crystallographic planes.
研究成果
The fabricated Si nanowire arrays exhibit ultra-low reflectance, strong polarization insensitivity, and omnidirectional light trapping properties, validated by experimental and theoretical methods. These findings enhance understanding of light-matter interactions in nanostructures and suggest applications in photonics and optoelectronics.
研究不足
The MACE process does not allow for fixed diameter and length control, leading to variations in nanowire dimensions. The study is limited to specific crystallographic planes and may not generalize to other orientations or materials.
1:Experimental Design and Method Selection:
The study employs metal-assisted chemical etching (MACE) to fabricate Si nanowire arrays on Si(100) and Si(111) substrates, with theoretical validation using COMSOL Multiphysics software and effective medium theory.
2:Sample Selection and Data Sources:
Single crystalline n and p type Si(111) and (100) substrates with thickness ~350 μm and resistivity 1-10 Ωcm are used.
3:List of Experimental Equipment and Materials:
Equipment includes UV-Vis spectrophotometer (UV-2600, Shimadzu), field emission scanning electron microscopy (FE-SEM, Zeiss Ultra-55), universal reflectance equipment (Perkin Elmer Lambda 950), micro-Raman system (Renishaw inVia), and chemicals like AgNO3, HF, H2O2, HNO
4:Experimental Procedures and Operational Workflow:
Substrates are cleaned, Ag nanoparticles deposited via electroless method, etched with HF/H2O2, Ag removed with HNO3, and samples dried. Reflectance and Raman measurements are performed.
5:Data Analysis Methods:
Data analyzed using COMSOL simulations for electromagnetic wave interactions, effective medium theory for refractive index calculations, and statistical methods for reproducibility.
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