研究目的
To evaluate the sub-surface damage of diamond wire-sawn monocrystalline silicon wafers in relation to sawing process parameters such as wire velocity and wire wear, focusing on residual stresses, amorphous silicon presence, and microcracks, and to assess their impact on solar cell manufacturing processes like texturing.
研究成果
The complementary use of Raman spectroscopy and SIREX polarimetry effectively characterizes sub-surface damage in diamond wire-sawn silicon wafers, revealing correlations between wire wear, velocity, amorphization, stress distribution, and microcrack depth. Findings suggest that fresh wires and lower velocities reduce amorphization and crack depth but may increase stress differences, offering insights for optimizing sawing processes in solar cell manufacturing.
研究不足
The study is limited to specific wire velocities and wear states; Raman mapping is time-consuming and covers only small areas; surface topography effects in SIREX are minimized but not fully eliminated; further analysis of high-stress regions is not conducted.
1:Experimental Design and Method Selection:
The study uses Raman spectroscopy and SIREX polarimetry as non-destructive, contactless optical methods for high-resolution stress imaging and phase analysis. Confocal laser scanning microscopy (CLSM) is used for microcrack depth measurement.
2:Sample Selection and Data Sources:
Monocrystalline silicon wafers (PV-grade Cz-silicon, p-type) sawn with wire velocities of 10 m/s, 15 m/s, and 20 m/s under constant feed rate, from fresh and used wire sides of a brick, are analyzed.
3:List of Experimental Equipment and Materials:
Equipment includes a Raman spectrometer (Bruker Optik GmbH), SIREX photo-elastic microscope (PVA TePla), confocal laser scanning microscope (CLSM), diamond wire saw (Meyer Burger DS264), and cleaning chemicals (sodium hydroxide, deionized water, Secco etch). Materials are silicon wafers and diamond wires.
4:Experimental Procedures and Operational Workflow:
Wafers are cleaned, then measured at five positions using Raman and SIREX for stress and amorphization analysis. Bevel-cut samples are prepared for CLSM microcrack depth measurement.
5:Data Analysis Methods:
Statistical analysis of Raman and SIREX maps, including mean values, standard errors, histograms, and correlation with microcrack depths.
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