研究目的
To develop a flowable chemical vapor deposition (FCVD) process for planarizing particle-scattered surfaces to improve the barrier properties of atomic layer deposition (ALD) Al2O3 thin films for encapsulation, particularly in flexible displays like OLEDs.
研究成果
The FCVD silicon oxide layer effectively planarizes particle-scattered surfaces, reducing the WVTR of ALD Al2O3 films from 2.0 × 10?3 to 1.2 × 10?3 g/(m2 · day) with particles present. This planarization effect is unique to FCVD and not observed with plasma polymer layers, making it a promising interlayer for improving barrier film performance in thin film encapsulation applications.
研究不足
The study was conducted at low temperatures suitable for flexible substrates but may not be applicable to high-temperature processes. The planarization effect was demonstrated with specific particle types and sizes; generalization to other contaminants may require further investigation. The WVTR measurement relies on accelerated testing, which might not fully replicate real-world conditions.
1:Experimental Design and Method Selection:
The study used an FCVD process with tetrabutoxysilane (TBOS) and O2 plasma in an inductively coupled plasma (ICP) reactor at room temperature to deposit flowable silicon oxide films for planarization. ALD was employed for Al2O3 deposition. Electrospraying was used to spread particles on substrates to simulate contamination.
2:Sample Selection and Data Sources:
Polyethylene naphthalate (PEN) substrates and Si (100) wafers were used. Particles included spherical PMMA and irregular Mg(OH)2 particles from AK ChemTech Co., Ltd.
3:List of Experimental Equipment and Materials:
ICP-CVD reactor, ALD chamber, FTIR spectrometer, FE-SEM (JSM7500F from JEOL), electrospray system, TBOS precursor, O2 gas, TMA precursor, Ar gas, DI water, UV-cured epoxy resin (TB3124L from 3M), Ca for WVTR measurement.
4:Experimental Procedures and Operational Workflow:
Particles were electrosprayed onto substrates. FCVD silicon oxide was deposited at room temperature with specific gas flows and pressure. ALD Al2O3 was deposited at 80°C. WVTR was measured using Ca oxidation tests under accelerated conditions (85°C, 85% RH).
5:Data Analysis Methods:
FTIR for chemical bonding analysis, FE-SEM for imaging planarization effects, electrical conductance measurements for WVTR calculation using a standard formula.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容