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过滤筛选
- 2019
- composite electrode
- silver nanowire
- reduced graphene oxide
- zinc oxide
- Optoelectronic Information Materials and Devices
- China Jiliang University
- Guangdong Poly-Optoelectronics Co.
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Photoactive and Non-Hazardous Kaolinite/ZnO Nanocomposite: Characterization and Reproducibility of the Preparation Process
摘要： Photoactive and non-hazardous kaolinite/ZnO nanocomposite with 50 wt.% of ZnO nanoparticles was prepared using simple and cheap hydrothermal method. The resulting solid phase was separated by decantation, and dried at 105 °C. Calcination of the nanocomposites at 600 °C led to the kaolinite—metakaolinite phase transformation, to further growth of ZnO crystallites, and to significant increase in photodegradation activity. Whereas, for the several applications, e.g., in brake industry, the larger amount of composites is needed, thus, the evaluation of the reproducibility of preparation process is one of the crucial parameter. Prepared nanocomposites were deeply characterized by using X-ray fluorescence spectroscopy, X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and Rietveld quantitative phase analysis. Photodegradation activity was evaluated by the discoloration of Acid Orange 7 aqueous solution under UV irradiation. All used analytical techniques and methods confirm the reproducibility of the preparation process and as well that ZnO nanoparticles are anchored tightly on the clay surface which prevents the release to the environment.
关键词： Nanocomposite,Rietveld,Kaolinite,Photoactivity,Zinc Oxide
更新于2025-09-23 15:22:29
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Effects of yttrium doping on the electrical performances and stability of ZnO thin-film transistors
摘要： In this paper, we have investigated the effects of yttrium (Y) doping on the electrical performance and stability of ZnO thin film transistors (TFTs). Here, Y-doped ZnO TFTs were fabricated by using radio frequency magnetron sputtering at 150 °C. As a result, the 1% Y-doped ZnO TFT exhibits a small threshold voltage shifts of 2.5 V under positive bias stress and ?2.8 V under negative bias stress as well as desirable device performance with field effect mobility of 9.8 cm2/V s, a subthreshold swing of 320 mV/decade and on/off current ratio of 107, respectively. Based on the XPS analysis and electrical characterizations, the improvement in stability and electrical properties of ZnO TFTs were attributed to the appropriate Y doping concentration, which not only could control the carrier concentration and broaden the band gap of ZnO film, but also suppress the oxygen vacancy defects and passivate the trap density at the SiO2/ZnO interfaces. Consequently, the high stability and excellent electrical performances of Y-doped ZnO TFTs show great potential for use in flat panel displays.
关键词： Doping,Zinc oxide (ZnO),Thin film transistors (TFTs),Bias stress stability
更新于2025-09-23 15:22:29
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A unique (4,4,5)-connected 3D zinc (II) metal-organic framework for highly efficient photodegradation of Rhodamine B under UV light
摘要： A new zinc (II) metal-organic framework, [Zn3(L)2(nbta)2]n (1) (L = 1,4-bis(benzimidazol-1-yl)-2-butene, H3nbta = 5-nitro-1,2,3-benzenetricarboxylic acid) was hydrothermally synthesized and structural characterized. 1 possesses a unique 3D (4,4,5)-connected network with a Schl?fla symbol of {42.63.8}2{44.62}{47.63}2. Furthermore, the photocatalytic property of 1 for degradation of the Rhodamine B (RhB) was examined under UV irradiation.
关键词： Semi-rigid bis(benzimidazole),Hydrothermal synthesis,Crystal structure,Metal-organic framework,Zinc (II),Photocatalytic degradation
更新于2025-09-23 15:22:29
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Effects of selenisation temperature on photoluminescence and photoluminescence excitation spectra of ZnO/CdS/Cu2ZnSnSe4/Mo/glass
摘要： The effect of solar cell processing (including etching in KCN along with deposition of CdS and ZnO) on photoluminescence (PL) spectra and bandgap Eg (measured at 4.2 K by photoluminescence excitation) of Cu2ZnSnSe4 films, produced by selenising metallic precursors at 450°C, 500°C and 550°C, was studied. Temperature and excitation intensity analysis of the P1 dominant band in the PL spectra of solar cells suggests that after processing this band still can be assigned to the free-to-bound recombination of free electrons with holes bound at deep acceptor levels influenced by valence band-tails. However processing increased the intensity of P1 and blue shifted it. The strongest effect was observed for the film selenised at 500°C. For the film selenised at 450°C the blue shift and increase in the intensity were smaller and only a slight intensity rise was found for the film selenised at 550°C. The intensity increase we assign to a reduction in the concentration of non-radiative recombination centers on the surface because of the etching and changes in doping due to inter-diffusion of Cd, S, Se and Zn after the deposition of CdS. Such an inter-diffusion depends on the elemental composition of the films defining the chemistry of defects and influencing Eg which increased in the film selenised at 500°C but decreased in the other films. Processing increased the P1 shift rate (j-shift) with excitation power change in all the films demonstrating a higher compensation degree in the solar cells which is consistent with the formation of an interface layer containing new donors CdCu.
关键词： Optical spectroscopy,Copper zinc tin selenide,Photoluminescence,Solar cells,Selenisation
更新于2025-09-23 15:22:29
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Mini submersible pump assisted sonochemical reactors: Large-scale synthesis of zinc oxide nanoparticles and nanoleaves for antibacterial and anti-counterfeiting applications
摘要： Low cost, environmentally friendly and industrial-scale approaches for the synthesis of anti-counterfeiting and antibacterial materials are a challenging task. The current research reports novel and inexpensive approaches for the synthesis of zinc oxide nanostructures (ZnO-NSs) using Mini Submersible Pump (MSP) assisted sonochemical reactors. Zinc oxide nanoleaves (ZnO-NLs) were synthesized using MSP assisted sonochemical mixing reactor at gram-scale (4 g). Zinc oxide nanoparticles (ZnO-NPs) were synthesized using MSP assisted sonochemical flow loop reactor at gram-scale (11.5 g). Synthesized ZnO-NSs were characterized by UV-visible spectroscopy, fluorescence spectroscopy, XRD, FTIR, TGA, BET, FEG-SEM, and FEG-TEM. Bare ZnO-NPs and ZnO-NPs coated cotton fabric showed high antibacterial activity against diseases causing Gram-positive bacteria Staphylococcus aureus. Based on the UV fluorescence property of the ZnO-NLs, invisible security ink was developed for anti-counterfeiting applications. The invisible security ink was tested as a rubber stamp and fountain pen inks which were found to be stable on the various kinds of microporous papers. As compared to our previously reported method, disperser assisted sonochemical approach for ZnO-NLs synthesis; the current approach reduces the cost of equipment used from ~1700 to 4 USD. Both reactors are designed simply (less complicated), based on an environmentally friendly approach, highly scalable, increases the effectiveness of the sonochemical technique and suitable for industrial applications.
关键词： antibacterial,anti-counterfeiting,sonochemical reactors,Mini submersible pump,zinc oxide nanoparticles and nanoleaves
更新于2025-09-23 15:22:29
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Facile Sol-gel Synthesis of Metaloxide Nanoparticles in a Cellulose Paper Template
摘要： Ensembles of free standing particles of titanium, zinc, copper and iron oxides of 6-109 nm in size were sol-gel synthesized with a use of a cellulose paper as a template. The calcination time as short as 60 min at 550°C in air was found to be sufficient for the formation of crystalline single phase TiO2 or ZnO nanoparticles, Cu2O+CuO or Fe2O3+Fe3O4 nanocomposites and to burn out the organic components. The impurities initially present in the cellulose (Сa, Na, Cl) were detected in the synthesized compounds.
关键词： Sol-gel synthesis,Zinc oxide,Nanoparticle,Copper oxides,Cellulose,Iron oxides,Titanium oxide
更新于2025-09-23 15:22:29
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Extremely Hydrophobic Zinc Oxide Micro/nanostructures on Stainless Steel Surfaces with Anti-biofilm Property
摘要： The extremely hydrophobic zinc oxide micro/nanostructures with microscale bundles and nanoscale rods were obtained by sol-gel method and hydrothermal method on stainless steel surfaces. The prepared extremely hydrophobic zinc oxide films were proven to possess excellent anti-biofilm property, which may lead to some new promising applications for inhibiting biofilm formation.
关键词： Hydrophobic surface,Zinc oxide,Anti biofilm
更新于2025-09-23 15:22:29
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Fabrication of IR windows grade zinc selenide by the reactive diffusive process
摘要： The preparation of infra-red windows grade zinc selenide (ZnSe) by the reactive diffusion process between liquid zinc and selenium was the goal of present work. In this regards, high purity zinc and Se elements with a nominal composition of Zn50Se50 were capsulated in quartz ampoule and annealed in the temperature range of 550-950 °C. The wurtzite structure of zinc selenide phase was successfully obtained during annealing process beyond 750 oC. The hexagonal structure of zinc selenide was an unstable phase and totally transformed to the cubic construction by increasing the annealing temperature (950 °C) that is appropriate for infra-red windows application. The formation of zinc selenide phase during the annealing process has been performed by the development of an unceasing layer of porous zinc selenide compound in zinc/ selenium interface. The formation of porous zinc selenide can be associated to the different diffusion constants of selenium and zinc atoms in zinc selenide lattice based on the Kirkendall theory.
关键词： Interfaces,zinc selenide.,Kinetics,Chalcogenides
更新于2025-09-23 15:22:29
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Optimization of formaldehyde detection performance based on Ni2+ sensitized monodisperse amorphous zinc tin oxide microcubes
摘要： The pure and Ni2+ sensitized monodisperse amorphous zinc tin oxide (a-ZTO) microcubes were synthesized via an in-situ precipitation method and subsequent wet impregnation. XPS results revealed that Ni2+ sensitization increased the relative content of chemisorbed oxygen and oxygen vacancies on the surface of a-ZTO microcubes. Compared to pure a-ZTO microcubes, 0.75 at% Ni2+ sensitized a-ZTO microcubes can significantly improve the gas sensing performance to formaldehyde at 200 °C, which may be attributed to its uniform morphology and modification of Ni2+ on the surface of a-ZTO microcubes. Further, the gas sensing mechanism is briefly discussed.
关键词： Surface sensitization,Zinc tin oxide,Monodisperse,Amorphous material,Sensors
更新于2025-09-23 15:22:29
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On the anomaly in the electrical characteristics of thin film transistors with multi-layered sol-gel processed ZnO
摘要： A set of bottom-gate Zinc Oxide (ZnO) thin film transistors (TFTs) with active layers containing 1, 4 and 8 layers of spin-coated ZnO were fabricated and their electrical characteristics such as transistor transfer and capacitance-voltage characteristics were analyzed. The transconductance of the single-layered ZnO transistor shows a single peak. On the other hand, multiple peaks and humps were observed in the transconductance and capacitance-voltage characteristics of multi-layered ZnO transistors. The multi-layers were grown by reiteration of the spin-coating process, producing ZnO-ZnO interlayer-interfaces. The surface of the ZnO layer in contact with the ambient contains active sites, resulting in chemisorption of ambient gases such as oxygen prior to the deposition of subsequent layers. The chemisorbed species become negatively-charged and form charge sheets, depleting the surface/interface region. It was proposed that the formation of depletion layers at ZnO-ZnO interlayer-interfaces is the main cause for the observed anomaly.
关键词： Sol-gel,Zinc oxide,Spin-coating,Thin-film transistors,Electrical Properties,Interface Defects
更新于2025-09-23 15:22:29