研究目的
To develop an instrument based on near-infrared absorption spectroscopy for trace moisture measurements in helium gas, addressing the demand from industries like combustion studies, semiconductor industry, environmental studies, and cryogenic services.
研究成果
The developed instrument is effective for trace moisture measurements in helium gas, with a sensitivity of ~17 ppmv for direct measurement and ~4 ppmv for 2-f measurement at 100 mb pressure. The method is fast, robust, and can be applied to other base gases.
研究不足
The sensitivity of the instrument is limited by interference fringes, and the method requires careful calibration and elimination of background absorption due to atmospheric air.
1:Experimental Design and Method Selection:
The instrument uses a laser modulated with both sinusoidal and slower linear scan, split into two beams for balanced detection between reference and measurement channels.
2:Sample Selection and Data Sources:
The experiment involves measuring moisture in helium gas at different concentrations and pressures.
3:List of Experimental Equipment and Materials:
Includes a DFB laser, beam splitter, absorption cell, photodiodes, and preamplifiers.
4:Experimental Procedures and Operational Workflow:
The laser beam is split, passed through air and an absorption cell, and the difference signal undergoes 2-f lock-in detection.
5:Data Analysis Methods:
The absorption spectra are computed using the Hitran and Exomol databases, with simulation and experimental results compared.
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