研究目的
To optimize the use of Boron spin on dopant (BSoD) as an alternative boron source for p+ emitter formation in n-type solar cells by addressing diffusion issues to achieve uniform sheet resistance.
研究成果
The BSoD diffused emitter can achieve sheet resistances ≤60?/□ with controlled process steps, showing promise for n-type solar cell applications. The removal of BRL improves minority carrier lifetimes, and PC1D simulation indicates a potential efficiency of 14.8%, suggesting BSoD as a viable alternative to BBr3.
研究不足
The study focuses on bare emitter surfaces without texturing and dielectric passivation, indicating potential for further efficiency improvement with these enhancements.
1:Experimental Design and Method Selection:
The study involves using BSoD for p+ emitter formation, focusing on process control steps to minimize diffusion issues.
2:Sample Selection and Data Sources:
Czochralski n-type c-Si wafers with specific resistivity and thickness are used.
3:List of Experimental Equipment and Materials:
Includes B200 spin on dopant source, acetone for dilution, tube furnace for diffusion, HF solution for BSG removal, and hot HNO3 for boron precipitate oxidation.
4:Experimental Procedures and Operational Workflow:
Involves RCA cleaning, BSoD deposition, diffusion at 850°C, in-situ oxidation, BSG removal, and characterization of sheet resistance, SIMS analysis, and minority carrier lifetimes.
5:Data Analysis Methods:
Sheet resistance measured with four-point probe, SIMS for B concentration profiles, QSSPC for minority carrier lifetimes, and PC1D simulation for efficiency estimation.
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