研究目的
To quantify the efficiency-determining processes in all-polymer solar cells and understand the impact of field-dependent charge separation on performance.
研究成果
Field-dependent charge separation limits the fill factor and thus the performance of all-polymer solar cells. The study successfully quantifies the efficiency-determining processes and demonstrates the utility of combining transient optical and electro-optical experiments with simulations to understand solar cell performance.
研究不足
The study focuses on a specific test system, and the findings may not be universally applicable to all all-polymer solar cells. The impact of field-dependent charge separation on performance is highlighted, but other factors may also play significant roles.
The study combines transient optical and electro-optical experiments to analyze the efficiency-determining processes in all-polymer solar cells. It involves the use of transient absorption spectroscopy, time-resolved photoluminescence, and time-delayed collection field experiments to quantify the yields of various photophysical processes. The experimental data is used to simulate current-voltage characteristics via drift-diffusion simulations to compare with experimentally measured values.
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Streak camera
Hamamatsu C10910
Hamamatsu
Used for time resolution in photoluminescence dynamics measurements.
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Titanium:sapphire amplifier
Coherent Legend Duo
Coherent
Used in transient absorption spectroscopy for generating probe pulses.
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Digital oscilloscope
LeCroy
LeCroy
Records the time evolution of EPR signal after pulsed photoexcitation.
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X-band EPR spectrometer
ELEXSYS E580
Bruker
Used for Electron Paramagnetic Resonance spectroscopy to investigate excited triplet states.
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Spin coater
Specialty Coating Systems Model G3P-8
Specialty Coating Systems
Used for depositing active layers of solar cells.
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Optical Parametric Oscillator
Radiantis Inspire HF-100
Radiantis
Used for time-resolved photoluminescence measurements to provide wavelength-tunable output.
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Ti:sapphire fs oscillator
Spectra Physics MaiTai
Spectra Physics
Pumps the Optical Parametric Oscillator for generating fs pulses.
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Q-switched Nd:YVO4 laser
INNOLAS piccolo AOT
INNOLAS
Provides excitation light for transient absorption spectroscopy.
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Solar simulator
Oriel Sol3A Class AAA
Oriel
Calibrated to 1 sun AM 1.5G for J-V measurements.
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