研究目的
Investigating the optical properties of CH3NH3PbI3 perovskite films deposited on meso-porous TiO2 by one step and hot casting techniques and their influence on the performance of perovskite solar cells.
研究成果
The study concludes that perovskite films created by OSM have higher optical absorption and better photovoltaic performance compared to those created by HCT. The difference in morphology and optical properties between the two methods significantly affects the efficiency of the resulting solar cells.
研究不足
The study focuses on the optical properties and does not extensively cover the electrical properties or long-term stability of the perovskite solar cells. The comparison is limited to two deposition techniques.
1:Experimental Design and Method Selection
The study compares the optical properties of CH3NH3PbI3 perovskite layers deposited on meso-porous TiO2 films via one step method (OSM) and hot casting technique (HCT). UV–Vis reflectance and transmittance spectroscopies were used to investigate the optical properties.
2:Sample Selection and Data Sources
Perovskite layers were prepared on meso-structured TiO2 scaffolds. The samples were characterized using UV-Vis-near IR Spectrophotometer equipped with an integrating sphere.
3:List of Experimental Equipment and Materials
Materials included CH3NH3I, PbI2, TiO2 paste, fluorine-doped tin oxide (FTO), and solvents like DMF and DMSO. Equipment included a LAMBDA 35 UV-Vis-near IR Spectrophotometer and a DC sputtering system for Au coating.
4:Experimental Procedures and Operational Workflow
Perovskite layers were deposited via spin coating using OSM and HCT. Optical measurements were conducted to obtain reflectance and transmittance spectra, from which optical constants were calculated.
5:Data Analysis Methods
Optical constants were calculated from the reflectance and transmittance spectra. The absorption coefficient, refractive index, extinction coefficient, and dielectric constants were determined. Optical band gaps were calculated using Tauc's power law.
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