研究目的
Investigating the adjustable optical transmittance of superhydrophobic carbon soot coatings by controlling their physicochemical profile through combustion conditions.
研究成果
The optical transmittance of soot coatings is governed by thickness, chemical state (sp2/sp3 ratio), and morphology, with enhanced transmittance in the NIR range for coatings with reduced π bonds. The findings enable single-step tuning of optical properties for potential underwater applications, leveraging the superhydrophobicity and anti-biofouling properties of soot coatings.
研究不足
Discrepancies in XPS data due to fitting software errors, potential variations in soot thickness from cutting procedures, and the complexity of simultaneously altered chemical state and morphology affecting optical interpretations.
1:Experimental Design and Method Selection:
The study used a combustion system to synthesize soot coatings by controlling air flow rates during rapeseed oil combustion, with in-situ manipulation of physicochemical properties. Methods included SEM, XPS, and spectrophotometry for characterization.
2:Sample Selection and Data Sources:
Glass slides (25x25 mm) were used as substrates for soot deposition. Soot was generated at three air flow rates (
3:0052, 0045, 0035 m3/min) to produce different morphologies:
quasispherical, mixed, and quasisquare.
4:List of Experimental Equipment and Materials:
Air pump, air flow meter/controller (Fisher Scientific 11998014), steel chimney, paper wick, rapeseed oil, glass slides (Medical Technics Engineering), SEM (Hitachi SU-70), XPS (ThermoFisher ESCALAB 250), spectrophotometer (LAMBDA 1050 UV/Vis/NIR, Perkin Elmer).
5:Experimental Procedures and Operational Workflow:
Ignite wick, control air flow, deposit soot on glass slides at varying times (15-120 s) and distances (30 mm). Characterize morphology, thickness, chemical composition, and optical transmittance.
6:Data Analysis Methods:
Image J software for thickness measurement, CASAXPS for XPS data fitting, Tauc model for optical data analysis.
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scanning electron microscope
SU-70
Hitachi
Used for morphological analysis of soot coatings
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X-ray photoelectron spectrometer
ESCALAB 250
ThermoFisher Scientific
Used for chemical state and composition analysis
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spectrophotometer
LAMBDA 1050
Perkin Elmer
Measures light transmission coefficient
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air flow meter/controller
11998014
Fisher Scientific
Provides adjustable air flow for combustion process
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glass slides
Medical Technics Engineering
Substrate for soot deposition
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