研究目的
To develop a simple one-step process for fabrication of an effective nanoparticulate mesoporous layer consisted of self-assembled MgO/TiO2 core/shell nanoparticles for mesostructured perovskite solar cells, aiming to passivate surface defects, reduce charge recombination, and improve the power conversion efficiency.
研究成果
The one-step fabrication of mesoporous layers consisting of self-assembled MgO/TiO2 core/shell nanoparticles significantly improves the photovoltaic performance of perovskite solar cells, achieving a power conversion efficiency increase from 13.13% to 16.30%. The MgO coating passivates surface defects, reduces charge recombination, and enhances charge extraction and injection, leading to higher open-circuit voltage and fill factor.
研究不足
The study focuses on the fabrication and performance of perovskite solar cells with MgO/TiO2 core/shell nanostructures but does not extensively explore long-term stability under operational conditions or scalability for industrial production.
1:Experimental Design and Method Selection:
A one-step bottom-up approach was used to fabricate mesoporous layers consisting of MgO/TiO2 core/shell nanoparticles.
2:Sample Selection and Data Sources:
Fluorine-doped tin oxide (FTO) transparent conducting glass was used as the substrate.
3:List of Experimental Equipment and Materials:
JSM-7500F field-emission scanning electron microscopy, JEM-2010F high resolution transmission electron microscopy, X’Pert Pro X-ray diffraction, Shimadzu UV-3600 spectrophotometer, QM 400 and Laser Strobe for photoluminescence measurements, F900 transient-state spectrophotometer for time-resolved PL spectra.
4:Experimental Procedures and Operational Workflow:
The mesoporous layer was spin-coated onto the compact electron transfer layer, followed by annealing and deposition of perovskite and hole transport layers.
5:Data Analysis Methods:
The photovoltaic performance was analyzed using J-V curves, IPCE spectra, and electrochemical impedance spectroscopy.
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