研究目的
To improve the photoelectric performance of perovskite solar cells (PSCs) by utilizing Au@Pt@Au core-shell nanoparticles synthesized through chemical reduction.
研究成果
PSC devices containing 1 wt.% Au@Pt@Au core-shell NPs had the best photovoltaic performances, attributed to the LSPR and scattering effects of the NPs. However, the efficacy of the photovoltaic parameters decreased with increased Au@Pt@Au core-shell NP loading due to the reorganization of electrons and holes and the decrease in electron travelling pathways.
研究不足
The recombination of electrons and holes on the surface of Au@Pt@Au core-shell NPs and the decrease in electron travelling pathways when excess Au@Pt@Au core-shell NPs are mixed into the devices.
1:Experimental Design and Method Selection:
Chemical reduction method for synthesizing Au@Pt@Au core-shell NPs.
2:Sample Selection and Data Sources:
Perovskite solar cells with carbon films as the counter electrode.
3:List of Experimental Equipment and Materials:
Transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis spectrophotometer, scanning electron microscope (SEM), electrochemical workstation.
4:Experimental Procedures and Operational Workflow:
Synthesis of Au@Pt@Au NPs, fabrication of PSC devices, characterization of physicochemical and photoelectric properties.
5:Data Analysis Methods:
Analysis of TEM images, optical absorption spectra, XRD patterns, XPS spectra, SEM cross-section images, UV-vis absorption spectra, J-V characteristics, histograms, and IPCE curves.
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