研究目的
Investigating the dual functional mechanism of light absorption and hole transport of Cu2CdxZn1-xSnS4 for achieving efficient and stable perovskite solar cells.
研究成果
The integration of Cd-doped CZTS and Au NRs into PSCs significantly improves the power conversion efficiency and extends the photoelectric response to the NIR region. The devices also exhibit enhanced stability under high humidity conditions, suggesting a promising approach for future PSC development.
研究不足
The study focuses on the integration of CZTS: Cd and Au NRs for enhancing PSC performance but does not explore the scalability of the fabrication process or the cost implications of using Au NRs.
1:Experimental Design and Method Selection:
The study employed thermal evaporation method for preparing Cu2CdxZn1-xSnS4 (CZTS: Cd) films and introduced Au nanorods (NRs) into the hole transporting layer (HTL) to enhance NIR light utilization.
2:Sample Selection and Data Sources:
ITO-coated glass substrates were used, and perovskite solution was prepared by mixing PbI2 and MAI in DMF: DMSO.
3:List of Experimental Equipment and Materials:
Equipment includes JEM-2100 electron microscope, UV-vis spectrophotometer, XPS, Class A solar simulator, SEM, XRD, AFM, and Fluorolog-3 spectrometer. Materials include ITO, SnO2, perovskite, CZTS: Cd, Spiro-OMeTAD, and Au NRs.
4:Experimental Procedures and Operational Workflow:
The process involved substrate preparation, perovskite film fabrication, CZTS: Cd layer deposition, Spiro-OMeTAD solution spin-coating, and Au electrode deposition.
5:Data Analysis Methods:
The study analyzed optical performance, photovoltaic parameters, and stability through various characterization techniques.
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UV-vis spectrophotometer
UV-1800
Shimadzu
Optical performance measurement
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SEM
SIRION
FEI
Surface and cross-section scanning electron microscope measurement
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XRD
D/max 2550
Rigaku
Crystal structure analysis
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AFM
5500
Agilent
Roughness measurement of the layers
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JEM-2100 electron microscope
JEM-2100
JEOL
Transmission electronic microscopy imaging
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XPS
ESCALAB MARK II
VG Inc.
Determination of compositions and chemical state of elements
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Class A solar simulator
ABET Sun 2000
ABET Technologies
Solar simulation for J-V curves measurement
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Fluorolog-3 spectrometer
Fluorolog-3
Horiba Jobin Yvon
Photoluminescence and time-resolved photoluminescence measurements
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