研究目的
Investigating the effects of modifying NiOx hole transport layer with NiOx nanoparticles on the charge carrier dynamic behaviors and photovoltaic performance of inverted perovskite solar cells.
研究成果
The modification of NiOx hole transport layer with NiOx nanoparticles significantly improves the photovoltaic performance of inverted perovskite solar cells by enhancing charge separation and transport, and reducing charge recombination. This work provides insights into the development of high-efficiency perovskite devices and understanding of charge carrier dynamics.
研究不足
The study focuses on the modification of NiOx hole transport layers and its effects on perovskite solar cells. Potential limitations include the scalability of the modification process and the long-term stability of the modified devices under operational conditions.
1:Experimental Design and Method Selection:
The study involves modifying a compact NiOx film with NiOx nanoparticles to explore its effects on charge carrier dynamics and photovoltaic performance.
2:Sample Selection and Data Sources:
Perovskite solar cells with modified and control NiOx hole transport layers were fabricated and characterized.
3:List of Experimental Equipment and Materials:
Instruments used include SEM, TEM, AFM, DLS, CA, XRD, UV-vis absorption, PL spectroscopy, TRPL, UPS, J-V characteristics, and IPCE measurement.
4:Experimental Procedures and Operational Workflow:
The NiOx films were modified with NiOx nanoparticles, and perovskite layers were deposited. The devices were then characterized for their photovoltaic performance and charge carrier dynamics.
5:Data Analysis Methods:
The data were analyzed using exponential fitting for TRPL, TPV, and TPC measurements to understand charge recombination and transport dynamics.
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SEM
Characterization of film morphology
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TEM
Visualization of nanoparticle morphology
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AFM
Examination of surface topography
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DLS
Measurement of particle size distribution
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CA
Investigation of infiltrating ability
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XRD
Characterization of crystal structures
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UV-vis absorption
Measurement of light absorption
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PL spectroscopy
Investigation of photoluminescence properties
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TRPL
Measurement of charge carrier lifetimes
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UPS
Measurement of Fermi energy levels
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J-V characteristics
Measurement of photovoltaic performance
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IPCE measurement
Measurement of incident photon-to-current efficiency
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