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All-Thin-Film Tandem Cells Based on Liquid Phase Crystallized Silicon and Perovskites

DOI:10.1109/JPHOTOV.2019.2896995 期刊:IEEE Journal of Photovoltaics 出版年份:2019 更新时间:2025-11-14 15:25:21
摘要: Combining the emerging perovskite solar cell technology with existing silicon approaches in a tandem cell design offers the possibility for new low-cost high-performance devices. In this study, the potential of liquid phase crystallized silicon (LPC-Si) solar cells as a bottom cell in an all-thin-film tandem device is investigated. By optimizing the current output of a four terminal tandem using optical simulations and state-of-the-art electrical properties of the top and bottom cells, we show that an efficiency of 23.3% can be reached, where 7.2% are attributed to the LPC-Si bottom cell. Including the potential of future developments of both sub cells, efficiencies of over 28% are estimated. Electrical and optical measurements of the bottom cell are performed by attaching a perovskite and a cutoff filter to the front side of the interdigitated back contacted LPC-Si cells. The measurements using a cutoff filter show a high impact of the filtered incident light spectrum on the open circuit voltage of the LPC-Si cell. A comparison of the simulated and measured absorptance shows that especially the optical properties of the transparent conductive oxides and recombination losses in the LPC-Si cause high current losses. Combining the measured data of the filtered LPC-Si cells and the semitransparent perovskite cells, yields a realistic estimation for the efficiency of a state-of-the-art four-terminal tandem device of 19.3%.
作者: Martina Trahms,Marko Jo?t,Cham Thi Trinh,Natalie Preissler,Steve Albrecht,Rutger Schlatmann,Bernd Rech,Daniel Amkreutz
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Investigating the potential of liquid phase crystallized silicon (LPC-Si) solar cells as a bottom cell in an all-thin-film tandem device with perovskites.

The paper presents a proof of concept for LPC-Si as a bottom cell in perovskite/LPC-Si tandem cells, with a state-of-the-art efficiency estimation of 19.3% and potential for 28.3% with future improvements. Key challenges include reducing parasitic absorption in TCOs and improving LPC-Si material quality. Future work should focus on detailed recombination analysis, light management enhancements, and developing monolithic tandem designs.

The study identifies limitations such as parasitic absorption in TCO layers, recombination losses in LPC-Si (indicating issues with bulk material quality and defects), and challenges in implementing front-side texturing without deteriorating electrical properties. The perovskite filter stability is limited when using index matching liquid in certain configurations.

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